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MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Inorganic ChemistryCoordination compounds

Choose the correct statement

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Inorganic ChemistryCoordination compounds

The correct order of magnetic moments (spin only) values in BM) among the following is (Atomic number: Mn = 25, Fe = 26, Co = 27)

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Inorganic ChemistryCoordination compounds

Which one of the following complex ion has the highest magnetic moment?

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Inorganic ChemistryCoordination compounds

Among the following complexes, which has a magnetic moment 5.9 BM ? Ni(CO)4, [Fe(H2O)6]2+, [Co(NH3)6]3+, [MnBr4]2–, [Zn(NH3)4]2+

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Inorganic ChemistryCoordination compounds

The correct order of magnetic moments (spin only values in B.M.) is

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Inorganic ChemistryCoordination compounds

Amongst[ Ni (CO)4], [Ni (CN)4]2– and [NiCl4]2

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Inorganic ChemistryCoordination compounds

Amongst the following, the lowest degree of paramagnetism per mole of the compound at 298 K will be shown by

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Inorganic ChemistryCoordination compounds

Spin only magnetic moment of the compound Hg[Co(SCN)4] is (a) (b) (c) (d)

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Inorganic ChemistryCoordination compounds

The compound having tetrahedral geometry is

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Inorganic ChemistryCoordination compounds

Among the following, the compound that is both paramagnetic and coloured is

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Inorganic ChemistryCoordination compounds

The effective atomic number of Cr (atomic no. 24) in [Cr(NH3)6]Cl3 is [Manipal 2010]

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Inorganic ChemistryCoordination compounds

[Cr(H2O)6]Cl3 (atomic number of Cr = 24) has a magnetic moment of 3.83 B.M. The correct distribution of 3d electrons in the chromium present in the complex is:

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Inorganic ChemistryCoordination compounds

Assign the hybridization, shape and magnetic moment of K3[Cu(CN)4]:

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Inorganic ChemistryCoordination compounds

An excess of AgNO3 is added to 100 mL of a 0.01 M solution of dichlorotetraaquachromium (III) chloride. The number of moles of AgCl precipitated would be (NEET 2013)

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Inorganic ChemistryCoordination compounds

The crystal field splitting energy for octahedral ( ) and tetrahedral ( t ) complexes is related as (a) t (b) t (c) t (d) t

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Inorganic ChemistryCoordination compounds

The magnitude of crystal field stabilization energy in tetrahedral complexes (CFSE of t ) is considerably less than that in the octahedral field because

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Inorganic ChemistryCoordination compounds

Cr3+ form four complexes with four different ligands which are [Cr(Cl)6]3–, [Cr(H2O)6]3+, [Cr(NH3)6]3+ and [Cr(CN)6]3–. The order of CFSE (0) in these complexes is in the order :

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Inorganic ChemistryCoordination compounds

The geometry of Ni(CO)4 and Ni(PPh3)2Cl2 are [Manipal 2006]

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Inorganic ChemistryCoordination compounds

The -bonded organometallic compound which has ethene as one of its component is [J&K CET]

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Inorganic ChemistryCoordination compounds

[Cr(H2O)6]Cl3 (at. no. of Cr = 24) has a magnetic moment of 3.83 BM, the correct distribution of 3d- electrons in the chromium of the complex is [CBSE AIPMT 2006] (a) xz x -y , x 3d 3d ,3d (b) xy x -y , 3d ,3d 3d , yz…

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Inorganic ChemistryCoordination compounds

Which one of the following is an outer orbital complex and exhibits paramagnetic behaviour? [CBSE AIPMT 2012]

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Inorganic ChemistryCoordination compounds

The chloride ion is detected by the formation of a white precipitate of AgCl on addition of aqueous AgNO3 solution and by the dissolution of the precipitate on addition of excess ammonia solution. AgCl dissolves in aq…

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Inorganic ChemistryCoordination compounds

The magnetic moment (spin only) of [NiCl4]2– is (AIPMT 2011)

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Inorganic ChemistryCoordination compounds

The pair in which both species have same magnetic moment (spin only value) is [AIIMS 2006]

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Inorganic ChemistryCoordination compounds

Which of the following facts about the complex [Cr(NH3)6]Cl3 is wrong? (AIPMT 2011)

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