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MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Inorganic ChemistryCoordination compounds

Which of the following statements is correct?

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Inorganic ChemistryCoordination compounds

The structures of Ni(CO)4 and Ni(PPh3)2Cl2 are

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Inorganic ChemistryCoordination compounds

Cobalt (III) chloride forms several octahedral complexes with ammonia. Which of the following will not give a test of chloride ions with silver nitrate at 25ºC? (AIPMT 2015)

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Inorganic ChemistryCoordination compounds

The correct order of the stoichiometries of AgCl formed when AgNO3 in excess is treated with the complexes: CoCl36NH3, CoCl35NH3, CoCl34NH3 respectively is (NEET 2017)

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Inorganic ChemistryCoordination compounds

Which of the following complex ions is paramagnetic?

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Inorganic ChemistryCoordination compounds

Which of the following complex ions is diamagnetic?

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Inorganic ChemistryCoordination compounds

Which of the following octahedral complex ions is diamagnetic?

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Inorganic ChemistryCoordination compounds

Which of the following is diamagnetic?

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Inorganic ChemistryCoordination compounds

The existence of two different coloured complexes with the composition [Co(NH3)4Cl2] + is due to [CBSE AIPMT2010]

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Inorganic ChemistryCoordination compounds

Which of the following complex ions/molecules of nickel is paramagnetic?

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Inorganic ChemistryCoordination compounds

The compound which does not show paramagnetism is

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Inorganic ChemistryCoordination compounds

Crystal field stabilisation energy for high spin d octahedral complex is [CBSE AIPMT2010]

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Inorganic ChemistryCoordination compounds

Which of the following complex ion is not expected to absorb visible light? [CBSE AIPMT 2010]

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Inorganic ChemistryCoordination compounds

Assertion: If 4 for [Cu(NH3)4] 2+ is 2.1 × 10 13, its instability constant is 4.76 × 10 –14. Reason: Overall dissociation equilibrium constant varies inversely with formation constant. [AIIMS2010]

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Inorganic ChemistryCoordination compounds

Which of the following species is expected to be colourless? [CBSE AIPMT 2010]

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Inorganic ChemistryCoordination compounds

The sum of coordination number and oxidation number of the metal M in the complex [M(en)2(C2O4)]Cl (where en is ethylenediamine) is (AIPMT 2015)

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Inorganic ChemistryCoordination compounds

Among [Ni(CO)4], [Ni(CN)4]2– and [NiCl4]2–

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Inorganic ChemistryCoordination compounds

[Sc(H2O)6]3+ ion is

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Inorganic ChemistryCoordination compounds

Four transition metal octahedral complexes, (the choice given below) low spin electron configurations arises only for [DPMT 2010]

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Inorganic ChemistryCoordination compounds

Among TiF6 2-, CoF6 3-, Cu2Cl2 and NiCl4 2- (atomic numbers of Ti = 22, Co = 27, Cu = 29, Ni = 28), the colourless species are

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Inorganic ChemistryCoordination compounds

The pair having the same magnetic moment is: [At, No. : Cr = 24, Mn = 25, Fe = 26, Co = 27]

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Inorganic ChemistryCoordination compounds

Which one of the following is wrongly matched?

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Inorganic ChemistryCoordination compounds

Among [NiCO4], [Ni(CN)4]2–, [NiCl4]2– species, the hybridisation states of the Ni atom are, respectively (At. no. of Ni = 28)

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Inorganic ChemistryCoordination compounds

The geometry of Ni (CO)4 and and Ni (P Ph3)2 Cl2 are

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Inorganic ChemistryCoordination compounds

Among the following complexes the one which shows zero crystal field stabilization energy (CFSE) is (AIPMT 2014)

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