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MEDIUMMCQ SINGLEJEE Mains ChemistryPhysical ChemistryIonic equilibrium

HCN is  a weak  acid (Ka =  6.2 ×  10–10).  NH4OH  is a weak base (Kb = 1.8 × 10–5). A 1M solution of NH4CN would be :

MEDIUMMCQ SINGLEJEE Mains ChemistryPhysical ChemistryIonic equilibrium

A physician wishes to prepare a buffer solution at pH = 3.58 that efficiently resists a change in pH yet contains only small conc. of the buffering agents. Which one of the following weak acid together with its sodium…

MEDIUMMCQ SINGLEJEE Mains ChemistryPhysical ChemistryIonic equilibrium

The  pH  of  blood  does  not  appreciably  change  by  a small addition of acid or a base because blood

MEDIUMMCQ SINGLEJEE Mains ChemistryPhysical ChemistryIonic equilibrium

How many moles of HCOONa must be added to 1L of 0.1 M HCOOH to prepare a buffer solution with a pH of  3.4  ?  (Given  :  Ka  for  HCOOH  =  2  ×  10 –4); (10-0.3 = 0.5)

MEDIUMMCQ SINGLEJEE Mains ChemistryPhysical ChemistryIonic equilibrium

The dissociation constant of HCN is 5 × 10 –10. The pH of the solution prepared by mixing 1.5 mole of HCN and  0.15  moles  of  KCN  in  water  and  making  up the total volume to 0.5 dm 3 is

MEDIUMMCQ SINGLEJEE Mains ChemistryPhysical ChemistryIonic equilibrium

In  a  mixture  of  a  weak  acid  and  its  salt, the  ratio  of concentration of acid to salt is increased ten-fold. The pH of the solution

MEDIUMMCQ SINGLEJEE Mains ChemistryPhysical ChemistryIonic equilibrium

The  pKa  value  of  NH3  is  5.  Calculate  the  pH  of  the buffer solution, 1 L of which contains 0.01 M NH4Cl and 0.10 M NH4OH

MEDIUMMCQ SINGLEJEE Mains ChemistryPhysical ChemistryIonic equilibrium

Consider the following solutions of equal concentrations. A = NH4Cl        B = CH3COONa C = NH4OH      D = CH3COOH A  buffer  solution  can  be  obtained  by  mixing  equal volumes of

MEDIUMMCQ SINGLEJEE Mains ChemistryPhysical ChemistryIonic equilibrium

Which of the following pairs constitutes a buffer?

MEDIUMMCQ SINGLEJEE Mains ChemistryPhysical ChemistryIonic equilibrium

Solution  of  0.1  N  NH4OH  and  0.1  N  NH4Cl  has  pH 9.25. The pKb of NH4OH is

MEDIUMMCQ SINGLEJEE Mains ChemistryPhysical ChemistryIonic equilibrium

A certain buffer solution contains equal concentration  of  X–  and  HX.  the  Ka  for  HX  is  10–8. The pH of the buffer is

MEDIUMMCQ SINGLEJEE Mains ChemistryPhysical ChemistryIonic equilibrium

One litre of a buffer solution containing 0.01 M NH4Cl and 0.1 M NH4OH having pKb of 5 has pH of

MEDIUMMCQ SINGLEJEE Mains ChemistryPhysical ChemistryIonic equilibrium

A buffer solution of pH 9 can be prepared by mixing

MEDIUMMCQ SINGLEJEE Mains ChemistryPhysical ChemistryIonic equilibrium

The acidic buffer solution can be prepared by mixing solutions of

MEDIUMMCQ SINGLEJEE Mains ChemistryPhysical ChemistryIonic equilibrium

Buffer  solution  can  be  obtained  by  mixing  aqueous solution of

MEDIUMMCQ SINGLEJEE Mains ChemistryPhysical ChemistryIonic equilibrium

A certain buffer solution contains equal concentration of  Xand HX. The Kb for  X is 10–10. The pH of the buffer is

MEDIUMMCQ SINGLEJEE Mains ChemistryPhysical ChemistryIonic equilibrium

Calculate the pH of a buffer prepared by mixing 0.10 mol of sodium formate and 0.05 mole of formic acid in 1.0 L of solution. [HCO2H : Ka =1.8 × 10–4]

MEDIUMMCQ SINGLEJEE Mains ChemistryPhysical ChemistryIonic equilibrium

What is the pH of a buffer solution which is 0.250 M in benzoic  acid,  C6H5COOH,  and  0.150  M  in  sodium benzoate, C6H5COONa, if a K  for benzoic acid is 6.5 × 10–5 ?

MEDIUMMCQ SINGLEJEE Mains ChemistryPhysical ChemistryIonic equilibrium

The principal buffer present in human blood is

MEDIUMMCQ SINGLEJEE Mains ChemistryPhysical ChemistryIonic equilibrium

For  preparing  a  buffer  solution  of  pH  6  by  mixing sodium  acetate  and  acetic  acid,  the  ratio  of  the concentration of salt and acid should be (Ka = 10 –5)

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryIonic equilibrium

When HCl gas is passed through a saturated solution of common salt, pure NaCl is precipitated because

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryIonic equilibrium

Which of the following is most soluble ?

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryIonic equilibrium

The solubility of PbCl2 is (a) sp K

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryIonic equilibrium

What is the value of Ksp for PbCl2 ?

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryIonic equilibrium

If the maximum concentration of PbCl2 in water is 0.01 M at 25ºC, its maximum concentration in 0.1 M NaCl will be

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