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MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryThermodynamics and Thermochemistry

A sample of liquid in a thermally insulated container (a calorimeter) is stirred by a motor. Taking liquid as a system for this process choose the appropriate option:

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryThermodynamics and Thermochemistry

Which of the following is an example of open system?

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryThermodynamics and Thermochemistry

In ….. process, work is done at the expense of internal energy.

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryThermodynamics and Thermochemistry

Based on the first law of thermodynamics, which one of the following is correct?

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryThermodynamics and Thermochemistry

Gaseous system is placed with pressure P₁, volume V₁ and  temperature  T1,  it  has  undergone  thermodynamic changes where temperature is remaining constant, it is

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryThermodynamics and Thermochemistry

U q w , is mathematical expression for

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryThermodynamics and Thermochemistry

A given mass of gas expands from state A to state B by three paths 1, 2, and 3 as shown in the figure: If w ,w  and w  respectively, be the work done by the gas along three paths, then (a) w w w (b) w w w

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryThermodynamics and Thermochemistry

The maximum work obtained by an isothermal reversible expansion of 1 mole of an ideal gas at 27°C from 2.24 to 22.4 L is (R = 2 cal)

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryThermodynamics and Thermochemistry

Calculate the work done when 1 mole of an ideal gas is compressed reversibly form 1 bar to 4 bar at a constant temperature of 300 K.

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryThermodynamics and Thermochemistry

The work done during the expansion of a gas from a volume of 4dm3 to 6 dm3 against a constant external pressure of 3 atm is

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryThermodynamics and Thermochemistry

Molar heat capacity of water in equilibrium with ice at constant pressure is

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryThermodynamics and Thermochemistry

1 mole of NH₃ gas at 27°C is expanded in reversible adiabatic condition to make volume 8 times (γ = 1.33). Final temperature and work done by the gas respectively are:

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryThermodynamics and Thermochemistry

According to the first law of thermodynamics, U q w . In special cases the statement can be expressed in different ways. Which of the following is not a correct expression?

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryThermodynamics and Thermochemistry

For the reaction, 2Cl(g) → Cl₂(g), the correct option is (NEET 2020)

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryThermodynamics and Thermochemistry

An ideal gas expands isothermally from 10–3 m3 to 10–2 m3 at 300 K against a constant pressure of 105 N m–2. The work done on the gas is (Odisha NEET 2019)

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryThermodynamics and Thermochemistry

In which case change in entropy is negative? (NEET 2019)

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryThermodynamics and Thermochemistry

For a given reaction, ∆H = 35.5 kJ mol–1 and ∆S = 83.6 J K–1 mol–1. The reaction is spontaneous at (Assume that ∆H and ∆S do not vary with temperature.) (NEET 2017)

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryThermodynamics and Thermochemistry

The bond dissociation energies of X2, Y₂ and XY are in the ratio of 1 : 0.5 : 1. ∆H for the formation of XY is – 200 kJ mol–1. The bond dissociation energy of X2 will be (NEET 2018)

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryThermodynamics and Thermochemistry

One mole of an ideal gas is initially at 0°C and 1 atm pressure. If it absorbs 1000 cal heat during a reversible isothermal expansion, what will be its final volume?

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryThermodynamics and Thermochemistry

G H T S when H S Hence, Correct option is c

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryThermodynamics and Thermochemistry

Assume each reaction is carried out in an open container. For which reaction will H = E ? (CBSE AIPMT 2006) (a) H (g) Br (g) 2HBr(g) → (b) C(s) 2H O(g) 2H (g) CO (g) → (c) PCl (g) PCl (g) Cl (g) → (d) 2CO(g) O (g) 2CO…

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryThermodynamics and Thermochemistry

Under isothermal conditions, a gas at 300 K expands from 0.1 L to 0.25 L against a constant external pressure of 2 bar. The work done by the gas is [Given that 1 L bar = 100 J] (NEET 2019)

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryThermodynamics and Thermochemistry

Thermodynamics deals with

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryThermodynamics and Thermochemistry

Which of the following is a path function?

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistrySolutions

If sodium sulphate is considered to be completely dissociated into cations and anions in aqueous solution, the change in freezing point of water ( Tf), when 0.01 mole of sodium sulphate is dissolved in 1 kg of water, …

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