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MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Inorganic Chemistryp -Block Elements (group 15-18)

Standard sodium thiosulphate solution is used in the estimation of iodine present in a solution. The equivalent weight of sodium thiosulphate which is required to make the standard solution is

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Inorganic Chemistryp -Block Elements (group 15-18)

When SO2 gas is passed into an acidified solution of K2Cr2O7, the oxidation state of chromium changes

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Inorganic Chemistryp -Block Elements (group 15-18)

Which of the following ions does not have an S—S linkage?

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Inorganic Chemistryp -Block Elements (group 15-18)

H2SO4 is manufactured from SO2(g) by the

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Inorganic Chemistryp -Block Elements (group 15-18)

Group 16 elements (except polonium) are called chalcogens because

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Inorganic Chemistryp -Block Elements (group 15-18)

The number of P—O—P bonds in cyclic metaphosphoric acid is

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Inorganic Chemistryp -Block Elements (group 15-18)

The number of P–O–P bonds in the structure of phosphorus pentoxide and phosphorus trioxide are respectively (2005)

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Inorganic Chemistryp -Block Elements (group 15-18)

Which of the following compounds consists of a P–P linkage?

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Inorganic Chemistryp -Block Elements (group 15-18)

Which of the following oxoacids of phosphorus is a reducing agent and a monobasic acid as well?

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Inorganic Chemistryp -Block Elements (group 15-18)

The true statement for the acids of phosphorus, H3PO2, H3PO3 and H3PO4 is

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Inorganic Chemistryp -Block Elements (group 15-18)

Which of the following structures represents hypophosphoric acid? (a) (b) (c) (d)

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Inorganic Chemistryp -Block Elements (group 15-18)

Which of the following statements is true for the H3PO3 molecule?

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Inorganic Chemistryp -Block Elements (group 15-18)

The reaction of white phosphorus with aqueous NaOH gives phosphine and another phosphorus containing compound. The reaction type, the oxidation states of phosphorus in phosphine and other product are respectively:

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Inorganic Chemistryp -Block Elements (group 15-18)

Syrupy H3PO4 is viscous due to

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Inorganic Chemistryp -Block Elements (group 15-18)

Solid PCl5 exists as

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Inorganic Chemistryp -Block Elements (group 15-18)

PH3 and NH3 on separate reaction with bleaching powder produce respectively

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Inorganic Chemistryp -Block Elements (group 15-18)

PCl5 on hydrolysis gives

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Inorganic Chemistryp -Block Elements (group 15-18)

White phosphorus reacts with NaOH to give PH3 and NaH2PO2. This reaction involves

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Inorganic Chemistryp -Block Elements (group 15-18)

On boiling phosphorus with KOH solution, product formed is

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Inorganic Chemistryp -Block Elements (group 15-18)

The reaction of P4 with X leads selectively to P4O6. The X is:

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Inorganic Chemistryp -Block Elements (group 15-18)

The percentage of p-character in the orbitals forming P–P bonds in P4 is:

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Inorganic Chemistryp -Block Elements (group 15-18)

Which of the following statements is correct regarding the behaviour of white phosphorus?

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Inorganic Chemistryp -Block Elements (group 15-18)

Red phosphorus is less reactive than white phosphorus because (a)the P—P bond length is greater in red phosphorus

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Inorganic Chemistryp -Block Elements (group 15-18)

The most stable allotropic form of phosphorus is

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Inorganic Chemistryp -Block Elements (group 15-18)

White phosphorus is more reactive than N2 because

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