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MEDIUMMCQ SINGLEJEE Advanced ChemistryInorganic Chemistryp-Block (group 13 and 14)

From B2H6, all the following can be prepared except:

MEDIUMMCQ SINGLEJEE Advanced ChemistryInorganic Chemistryp-Block (group 13 and 14)

o o Re d hot 100 C 160 C H BO X Y B O ; ¾¾¾® ¾¾¾® ¾¾¾® X and Y respectively are:

MEDIUMMCQ SINGLEJEE Advanced ChemistryInorganic Chemistryp-Block (group 13 and 14)

When strongly heated, orthoboric acid leaves a residue of:

MEDIUMMCQ SINGLEJEE Advanced ChemistryInorganic Chemistryp-Block (group 13 and 14)

Na B O X H BO . + ® What is X in the reaction ?

MEDIUMMCQ SINGLEJEE Advanced ChemistryInorganic Chemistryp-Block (group 13 and 14)

Which of the statement is true for the above sequence of reactions?

MEDIUMMCQ SINGLEJEE Advanced ChemistryInorganic Chemistryp-Block (group 13 and 14)

Boric acid is used in carrom boards for smooth gliding of pawns because:

MEDIUMMCQ SINGLEJEE Advanced ChemistryInorganic Chemistryp-Block (group 13 and 14)

In the structure of diborane

MEDIUMMCQ SINGLEJEE Advanced ChemistryInorganic Chemistryp-Block (group 13 and 14)

Na2B4O7.10H2O is correctly represented as:

MEDIUMMCQ SINGLEJEE Advanced ChemistryInorganic Chemistryp-Block (group 13 and 14)

Which of the following is not true regarding the nature of halides of boron ?

MEDIUMMCQ SINGLEJEE Advanced ChemistryInorganic Chemistryp-Block (group 13 and 14)

Which of the following is a false statement ?

MEDIUMMCQ SINGLEJEE Advanced ChemistryInorganic Chemistryp-Block (group 13 and 14)

The power of halides of boron to act as Lewis acids decreases in the order:

MEDIUMMCQ SINGLEJEE Advanced ChemistryInorganic Chemistryp-Block (group 13 and 14)

The main factor responsible for weak acidic nature of B—F bonds in BF3 is:

MEDIUMMCQ SINGLEJEE Advanced ChemistryInorganic Chemistryp-Block (group 13 and 14)

BCl3 does not exist as a dimer but BH3 exists as B2H6 because

MEDIUMMCQ SINGLEJEE Advanced ChemistryInorganic Chemistryp-Block (group 13 and 14)

BF3 is used as catalyst in several industrial processes due to its:

MEDIUMMCQ SINGLEJEE Advanced ChemistryInorganic Chemistryp-Block (group 13 and 14)

The decreasing order of power of boron halides to act as Lewis acids is (a) BF BCl BBr > > (b) BBr BCl BF > > (c) BCl BF BBr > > (d) BCl BBr BF > >

MEDIUMMCQ SINGLEJEE Advanced ChemistryInorganic Chemistryp-Block (group 13 and 14)

In BX3, B – X distance is shorter than what is expected theoretically because (X = F, Cl, Br, I)

MEDIUMMCQ SINGLEJEE Advanced ChemistryInorganic Chemistryp-Block (group 13 and 14)

Identify X and Y in the following reaction. NaBH 140ºC C H Cl BCl NH Cl X Y + ¾¾¾¾® ¾¾¾¾®

MEDIUMMCQ SINGLEJEE Advanced ChemistryInorganic Chemistryp-Block (group 13 and 14)

A gas other than HCl is obtained in : (a) Silent electric discharge BCl + H ¾¾¾¾¾® (b) LiAlH + BF ®

MEDIUMMCQ SINGLEJEE Advanced ChemistryInorganic Chemistryp-Block (group 13 and 14)

Which of the following statements about anhydrous alu- minium chloride is correct?

MEDIUMMCQ SINGLEJEE Advanced ChemistryInorganic Chemistryp-Block (group 13 and 14)

Which is not the use of orthoboric acid ?

MEDIUMMCQ SINGLEJEE Advanced ChemistryInorganic Chemistryp-Block (group 13 and 14)

Borax is not used

MEDIUMMCQ SINGLEJEE Advanced ChemistryInorganic Chemistryp-Block (group 13 and 14)

Which is the hardest compound of boron ?

MEDIUMMCQ SINGLEJEE Advanced ChemistryInorganic Chemistryp-Block (group 13 and 14)

Which of the following is the electron deficient molecule ?

MEDIUMMCQ SINGLEJEE Advanced ChemistryInorganic Chemistryp-Block (group 13 and 14)

Which of the following compounds are formed when BCl3 is treated with water ?

MEDIUMMCQ SINGLEJEE Advanced ChemistryInorganic Chemistryp-Block (group 13 and 14)

The geometry of a complex species can be understood from the knowledge of type of hybridisation of orbitals of central atom. The hybridisation of orbitals of central atom in [B(OH)4]– and the geometry of the complex a…

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