19,000+ solved questions for JEE Advanced, JEE Mains, NEET & IChO — with answers and expert explanations.
105. (∆U – ∆H) for the formation of NH₃ from N₂ and H₂ is :
H for the reaction, C(graphite) 2H (g) CH (g) → at 298 K and 1 atm is – 17900 cal. The E for the above conversion would be
The heat of formation of Fe O s is –824.2 kJ mol–1. ∆H for the reaction. 2Fe O s 4Fe s 3O g → is:
The standard enthalpies of formation of HCl(g), H (g) and Cl₂(g) are –92.2, 217.7 and 121.4 kJ mol-1 respectively. The bond dissociation energy of HCl is:
∆H for the reaction, SO g O g SO g ∆H = –98.3 kJ If the enthalpy of formation of SO₃(g) is –395.4 kJ then the enthalpy of formation of SO₂(g) is :
For the reaction, 2H O g 2H g O g → ∆H = 571.6 KJ fH of water is :
For the reaction, 8 g 2 g 2 g l C H 5O 3CO 4H O → at constant temperature, H E is (2003)
The densities of graphite and diamond at 298 K are 2.25 and 3.31 g cm–3, respectively. If the standard free energy difference is equal to 1895 J mol–1, the pressure at which graphite will be transformed into diamond a…
When 0.5 g of sulphur is burnt to SO₂ 4.6 kJ of heat is liberated. What is the enthalpy of formation of sulphurdioxide?
The molar heat capacity of water at constant pressure, C, is 75J K-1. When 1.0 kJ of heat is supplied to 100 g of water which is free to expand, the increase in temperature of water is. (2003)
The following data is known about the melting of a compound AB. ∆H = 9.2 kJ mol–1. ∆S = 0.008 kJ K–1mol–1. Its melting point is :
Consider the following reaction –1 (aq) (aq) (l) –1 2(g) 2(g) (l) 2(g) 2(g) (g) (l) –1 2(g) 2(g) 2(g) (l) –1 (i)H OH H O , H X kJ mol (ii)H 1/ 2O H O , H X kJ mol (iii)CO H CO H O , H X kJ mol (iv)C H 5 / 2O 2CO H O ,…
Cell reaction is spontaneous when (a) G is negative (b) G is positive (c) red G is positive (d) red G is negative
Enthalpy change for the reaction, 4H(g) → 2H₂(g) is – 869.5 kJ. The dissociation energy of H–H bond is
2 moles of ideal gas at 27°C temperature is expanded reversibly from 2 lit. to 20 lit. find entropy change. (R = 2 cal/mol K)
Which of the following reactions define o f G ? (a) diamond C O g CO g → (b) H g F g HF g → (c) H P O H O 2H PO → (d) SO g O g SO g →
In which of the following cases, the reaction is spontaneous at all temperatures ?
A reaction has ∆H = – 33 kJ and ∆S = +58 J/K. This reaction would be :
It is impossible for a reaction to take place if (a) H is +ve and S is +ve (b) H is –ve and S is +ve (c) H is +ve and S is –ve (d) H is –ve and S is –ve
Pick out the wrong statement
In which case change in entropy is negative?
Unit of entropy is
The entropy change when two moles of ideal monoatomic gas is heated from 200°C to 300°C reversibly and isochorically?
G H T S when H S Hence, Correct option is c
G T S when H