19,000+ solved questions for JEE Advanced, JEE Mains, NEET & IChO — with answers and expert explanations.
The standard enthalpies of formation of HCl(g), H (g) and Cl₂(g) are –92.2, 217.7 and 121.4 kJ mol-1 respectively. The bond dissociation energy of HCl is:
Three moles of an ideal gas expanded spontaneously into vacuum. The work done will be (Mains 2010)
Which of the following statements is correct for the spontaneous adsorption of a gas? (2014)
The following data is known about the melting of a compound AB. ∆H = 9.2 kJ mol–1. ∆S = 0.008 kJ K–1mol–1. Its melting point is :
The densities of graphite and diamond at 298 K are 2.25 and 3.31 g cm–3, respectively. If the standard free energy difference is equal to 1895 J mol–1, the pressure at which graphite will be transformed into diamond a…
Which one of the following is not always negative?
For the reaction, 2H O g 2H g O g → ∆H = 571.6 KJ fH of water is :
The enthalpy of vaporisation of a compound AB at its boiling point (127°C) is 6.4 kJ mol-1. Its entropy of vaporization is
In a reaction P + Q → R + S, there is no change in entropy. Enthalpy change for the reaction (∆H) is 12 kJ mol–1. Under what conditions, reaction will have negative value of free energy change?
Enthalpy change for the reaction, 4H(g) → 2H₂(g) is – 869.5 kJ. The dissociation energy of H–H bond is
Cell reaction is spontaneous when (a) G is negative (b) G is positive (c) red G is positive (d) red G is negative
Which of the following reactions define o f G ? (a) diamond C O g CO g → (b) H g F g HF g → (c) H P O H O 2H PO → (d) SO g O g SO g →
∆H for the reaction, SO g O g SO g ∆H = –98.3 kJ If the enthalpy of formation of SO₃(g) is –395.4 kJ then the enthalpy of formation of SO₂(g) is :
In which of the following cases, the reaction is spontaneous at all temperatures ?
H and E for the reaction, Fe O s 3H g 2Fe s H O l → at constant temperature are related as (a) H E (b) H E RT (c) H E RT (d) H E 3RT
Which one among the following is the correct option for right relationship between CP and CV for one mole of ideal gas? (NEET 2021)
Pick out the wrong statement
It is impossible for a reaction to take place if (a) H is +ve and S is +ve (b) H is –ve and S is +ve (c) H is +ve and S is –ve (d) H is –ve and S is –ve
Which one of the following is correct? (a) G H T S
One mole of an ideal diatomic gas (Cv = 5 cal) was transformed from initial 25°C and 1 L to the state when temperature is 100°C and volume 10 L. The entropy change of the process can be expressed as (R = 2 calories/mo…
When one mole of an ideal gas is compressed to half of its initial volume and simultaneously heated to twice its initial temperature, the change in entropy of gas (∆S) is :
A reaction has ∆H = – 33 kJ and ∆S = +58 J/K. This reaction would be :
For the gas phase reaction, PCl g PCl g Cl g Which of the following conditions are correct?
Unit of entropy is
Considering entropy (s) as a thermodynamic parameter, the criterion for the spontaneity of any process is (a) system surroundings S S (b) system surroundings S S (c) system S 0 only (d) surroundings S 0only