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HARDMCQ SINGLENEET ChemistryPhysical ChemistryIonic equilibrium

What is the equilibrium [OH–] in 0.1413 M H₂CO₃ ? H CO H O H O HCO (Ka = 4.30 ×10–7)

HARDMCQ SINGLENEET ChemistryPhysical ChemistryIonic equilibrium

A mixture of weak acid is 0.1 M in HCOOH a K 1.8 10 x and 0.1 M in HOCN a K 3.1 10 x Hence, [H O ]  is

HARDMCQ SINGLENEET ChemistryPhysical ChemistryIonic equilibrium

The equilibrium constant for this reaction is approximately 10–3. HPO (aq.) HCO (aq.) H PO (aq.) CO (aq.) Which is the strongest conjugate base in this reaction? (a) HPO (aq.) (b) HCO (aq.) (c) H PO (aq.) (d) CO (aq.)

HARDMCQ SINGLENEET ChemistryPhysical ChemistryIonic equilibrium

Consider  the  following  reaction  which  proceeds predominantly forward HSO NH NH SO From the information given it is clear that (a) HSOis a stronger acid than NH.

HARDMCQ SINGLENEET ChemistryPhysical ChemistryIonic equilibrium

Assertion: When aqueous, solution of CH₃COONH₄ is diluted, then its degree of hydrolysis increases. Reason:  Ammonium  acetate  is  the  salt  of  weak  acid and  weak  base;  its  degree  of  hydrolysis  does  not de…

HARDMCQ SINGLENEET ChemistryPhysical ChemistryIonic equilibrium

Assertion: Aqueous  solution of  ammonium  carbonate is basic. Reason: Acidic or Basic nature of a salt solution of a salt  of  weak  acid  and  weak  base  depends  on  Ka  and Kb of the acid and base forming it.

HARDMCQ SINGLENEET ChemistryPhysical ChemistryIonic equilibrium

Assertion: If a K  of HA is 10–3 and a K  of HB is 10 at 25ºC, pH of an aqueous solution of HB will be one unit greater than pH of equimolar solution of HA. Reason:  For  weak  acids,  both  concentration  and ionizat…

HARDMCQ SINGLENEET ChemistryPhysical ChemistryIonic equilibrium

Assertion: pH of 10–8 M HCl lies between 6 and 7. Reason:  For  very  dilute  solutions  of  acids,  H⁺  ion contribution from water is also taken into consideration.

HARDMCQ SINGLEJEE Mains ChemistryPhysical ChemistryIonic equilibrium

A buffer is prepared by adding 0.30 mol CH₃COONa to 2.0  L  of  a  0.10  M  CH₃COOH  solution.  Calculate the eq K /c (x y) eq K c/(xy) 1/(x y) x y 1 x y eq K /c x y eq K /xyc pH  after  0.030  mol  HCl  are  added  t…

HARDMCQ SINGLEJEE Mains ChemistryPhysical ChemistryIonic equilibrium

The  solubility  of  CaCO₃  is  7  mg/L.  Calculate  the solubility product of BaCO₃ from this information and from  the  fact that  when  Na₂CO₃  is added slowly  to  a solution  containing  equimolar  concentration …

HARDMCQ SINGLEJEE Mains ChemistryPhysical ChemistryIonic equilibrium

The solubility of AgCl is maximum in

HARDMCQ SINGLEJEE Mains ChemistryPhysical ChemistryIonic equilibrium

The solubility of LiOH in a solution with pH = 8 is (Ksp = 1.8 × 10–12)

HARDMCQ SINGLEJEE Mains ChemistryPhysical ChemistryIonic equilibrium

Assertion (A): pH of HCl solution is less than that of acetic acid of the same concentration. Reason (R):  In  equimolar  solutions,  the  number  of titrable protons present in HCl in less than that present in acetic…

HARDMCQ SINGLEJEE Mains ChemistryPhysical ChemistryIonic equilibrium

Assertion: If HA and HB are two weak non-basic acids with Ka(HA)  < Kb(HB), then, the aqueous solution  of NaA will have higher pH than pH of aqueous solution of NaB of same concentration. Reason: Conjugate base of  a…

HARDMCQ SINGLEJEE Mains ChemistryPhysical ChemistryIonic equilibrium

Assertion: When aqueous, solution of CH₃COOAg is diluted, then its degree of hydrolysis increases. Reason:  Silver  acetate  is  the  salt  of  weak  acid  and weak base; its degree of hydrolysis does not depend on th…

HARDMCQ SINGLEJEE Mains ChemistryPhysical ChemistryIonic equilibrium

Assertion: When aqueous, solution of CH₃COONH₄ is diluted, then its degree of hydrolysis increases. Reason:  Ammonium  acetate  is  the  salt  of  weak  acid and  weak  base;  its  degree  of  hydrolysis  does  not de…

HARDMCQ SINGLEJEE Mains ChemistryPhysical ChemistryIonic equilibrium

Assertion: Aqueous  solution of  ammonium  carbonate is basic. Reason: Acidic or Basic nature of a salt solution of a salt  of  weak  acid  and  weak  base  depends  on  Ka  and Kb of the acid and base forming it.

HARDMCQ SINGLEJEE Mains ChemistryPhysical ChemistryIonic equilibrium

Assertion: If a K  of HA is 10–3 and a K  of HB is 10 at 25ºC, pH of an aqueous solution of HB will be one unit greater than pH of equimolar solution of HA. Reason:  For  weak  acids,  both  concentration  and ionizat…

HARDMCQ SINGLEJEE Mains ChemistryPhysical ChemistryIonic equilibrium

Assertion: pH of 10–8 M HCl lies between 6 and 7. Reason:  For  very  dilute  solutions  of  acids,  H⁺  ion contribution from water is also taken into consideration.

HARDMCQ SINGLEJEE Mains ChemistryPhysical ChemistryIonic equilibrium

Assertion: pH  of  water  increases  with  an  increase  in temperature. Reason: Kw  of  water  increases  with  increase  in temperature.

HARDMCQ SINGLEJEE Mains ChemistryPhysical ChemistryIonic equilibrium

Assertion: Addition  of  HCl(aq.)  to  HCOOH(aq.) decreases the ionization of HCOOH. Reason:  Common  ion  effect  of  H⁺  ion,  reduces  the ionization of HCOOH.

HARDMCQ SINGLEJEE Mains ChemistryPhysical ChemistryIonic equilibrium

Assertion (A): H₂SO₄ acts as a base in the presence of HClO₄. Reason (R): Perchloric  acid  is  stronger  acid  than H₂SO₄.

HARDMCQ SINGLEJEE Mains ChemistryPhysical ChemistryIonic equilibrium

The solubility products of MA, MB, MC and MD are 1.8 × 10–10, 4 × 10–3, 4 × 10–8 and 6 × 10–5 respectively. If  a  0.01  M  solution  of  MX  is  added  dropwise  to  a mixture containing A–, B–, C– and D– ions then t…

HARDMCQ SINGLEJEE Mains ChemistryPhysical ChemistryIonic equilibrium

Ksp of Mg (OH)₂ is 1 × 10–12. 0.01 M Mg (OH)₂ will be precipitating at the limiting pH :

HARDMCQ SINGLEJEE Mains ChemistryPhysical ChemistryIonic equilibrium

Calculate  the  concentration  of  H⁺  ion  in  mol/L  of 0.010M solution of NH₄Cl? (Kb = 1.8 × 10–6)

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