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HARDMCQ SINGLENEET ChemistryPhysical ChemistryThermodynamics and Thermochemistry

When 1 mol of an ideal gas is compressed to half of its volume, its temperature becomes double; then the change in entropy (S) would be:

HARDMCQ SINGLENEET ChemistryPhysical ChemistryThermodynamics and Thermochemistry

Consider the reaction below at 298 K: C (graphite) + 2H₂ (g) → CH₄ (g) →fHº (kJ/mol) – 74.9 S₀ m(J/K/mol + 5.6 + 130.7 Which statement below is correct ?

HARDMCQ SINGLENEET ChemistryPhysical ChemistryThermodynamics and Thermochemistry

Which of the following are extensive properties?

HARDMCQ SINGLENEET ChemistryPhysical ChemistryThermodynamics and Thermochemistry

Assertion: For an isolated system, q is zero. Reason: In an isolated system, change in U and V is zero.

HARDMCQ SINGLENEET ChemistryPhysical ChemistryThermodynamics and Thermochemistry

A diatomic gas at pressure P, compressed adiabatically to half of its volume, what is the final pressure?

HARDINTEGERNEET ChemistryPhysical ChemistryThermodynamics and Thermochemistry

If one monoatomic gas is expanded adiabatically from 2L to 10L at 1 atm external pressure then the value of U (in atm L) is

HARDMCQ SINGLENEET ChemistryPhysical ChemistryThermodynamics and Thermochemistry

For which of the following cases H S T ?

HARDMCQ SINGLENEET ChemistryPhysical ChemistryThermodynamics and Thermochemistry

What is the entropy change in 2 mol N₂, when its temperature is taken from 400 K to 800 K. at constant pressure?

HARDMCQ SINGLENEET ChemistryPhysical ChemistryThermodynamics and Thermochemistry

Assertion: In isothermal process, whole of heat energy supplied to the system is converted into internal energy. Reason: According to the first law of thermodynamics U = q - w

HARDMCQ SINGLENEET ChemistryPhysical ChemistryThermodynamics and Thermochemistry

Which thermodynamic parameter is not a state function?

HARDMCQ SINGLENEET ChemistryPhysical ChemistryThermodynamics and Thermochemistry

The magnitudes of enthalpy changes for irreversible adiabatic expansion of a gas from 1L to 2L is H₁ and for reversible adiabatic expansion for the same expansion is H₂. Then

HARDMCQ SINGLENEET ChemistryPhysical ChemistryThermodynamics and Thermochemistry

Match List I with List II and select the correct answer using the codes given below the lists: List – I List – II A. T G P

HARDMCQ SINGLEJEE Mains ChemistryPhysical ChemistryThermodynamics and Thermochemistry

Find rH at 320 K for the reaction is:

HARDMCQ SINGLEJEE Mains ChemistryPhysical ChemistryThermodynamics and Thermochemistry

1 mole of an ideal gas expands isothermally reversibly from 2 litre to 4 litre and 3 moles of the same gas expands from 2 litre to x litre and doing same work, what is ‘x’?

HARDINTEGERJEE Mains ChemistryPhysical ChemistryThermodynamics and Thermochemistry

The heat liberated when 1.89g of benzoic acid is burnt in a bomb calorimeter at 25 °C and it increases the temperature of 18.94 kg of water by 0.632 °C. if the specific heat of water at 25 °C is 0.998 cal/g- °C, the v…

HARDMCQ SINGLEJEE Mains ChemistryPhysical ChemistryThermodynamics and Thermochemistry

A liquid which is confined inside an adiabatic piston is suddenly taken from state 1 to state 2 by a single stage process. If the piston comes to rest at point 2 as shown. Then the enthalpy change for the process will…

HARDMCQ SINGLEJEE Mains ChemistryPhysical ChemistryThermodynamics and Thermochemistry

Assertion: A reaction which is spontaneous and accompanied by decrease of randomness must be exothermic. Reason: All exothermic reactions are accompanied by decrease in randomness.

HARDMCQ SINGLEJEE Mains ChemistryPhysical ChemistryThermodynamics and Thermochemistry

A system undergoes a 3-step process. In step 1, 25 J of work is done by the system as its internal energy (U) decreases by 50 J. In step 2, w = -15J and q = +40J. In step 3 at constant volume, the system gives off 50 …

HARDMCQ SINGLEJEE Mains ChemistryPhysical ChemistryThermodynamics and Thermochemistry

Assertion: Entropy of system increases for a spontaneous reaction. Reason: Enthalpy of reaction always not decreases for spontaneous reaction.

HARDMCQ SINGLEJEE Mains ChemistryPhysical ChemistryThermodynamics and Thermochemistry

A system undergoes a 2-step process. In step 1, 15 J of work is done on the system as its internal energy increases by a total of 30 J. In step 2, at constant volume, the system decreases its internal energy by 20 J. …

HARDMCQ SINGLEJEE Mains ChemistryPhysical ChemistryThermodynamics and Thermochemistry

A diatomic gas at pressure P, compressed adiabatically to half of its volume, what is the final pressure?

HARDMCQ SINGLEJEE Mains ChemistryPhysical ChemistryThermodynamics and Thermochemistry

Find r S at 320 K for the reaction is:

HARDMCQ SINGLEJEE Mains ChemistryPhysical ChemistryThermodynamics and Thermochemistry

Assertion: In isothermal process, whole of heat energy supplied to the system is converted into internal energy. Reason: According to the first law of thermodynamics U = q - w

HARDMCQ SINGLEJEE Mains ChemistryPhysical ChemistryThermodynamics and Thermochemistry

Assertion: For an isolated system, q is zero. Reason: In an isolated system, change in U and V is zero.

HARDMCQ SINGLEJEE Mains ChemistryPhysical ChemistryThermodynamics and Thermochemistry

Assertion: There is no change in internal energy for an ideal gas at constant temperature. Reason: Internal energy of an ideal gas is a function of temperature only.

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