19,000+ solved questions for JEE Advanced, JEE Mains, NEET & IChO — with answers and expert explanations.
If one monoatomic gas is expanded adiabatically from 2L to 10L at 1 atm external pressure then the value of U (in atm L) is
Assertion: Entropy of system increases for a spontaneous reaction. Reason: Enthalpy of reaction always not decreases for spontaneous reaction.
Assertion: Entropy is always constant for a closed system. Reason: Closed system is always reversible.
The heat liberated when 1.89g of benzoic acid is burnt in a bomb calorimeter at 25 °C and it increases the temperature of 18.94 kg of water by 0.632 °C. if the specific heat of water at 25 °C is 0.998 cal/g- °C, the v…
Match List I with List II and select the correct answer using the codes given below the lists: List – I List – II A. T G P
A system undergoes a 2-step process. In step 1, 15 J of work is done on the system as its internal energy increases by a total of 30 J. In step 2, at constant volume, the system decreases its internal energy by 20 J. …
Assertion: A reaction which is spontaneous and accompanied by decrease of randomness must be exothermic. Reason: All exothermic reactions are accompanied by decrease in randomness.
Assertion: Entropy of system increases for a spontaneous reaction. Reason: Enthalpy of reaction always not decreases for spontaneous reaction.
Assertion: For an isolated system, q is zero. Reason: In an isolated system, change in U and V is zero.
Assertion: Addition of Q and w gives ΔU. Reason: Addition of two path functions cannot give state function.
Find r S at 320 K for the reaction is:
For which of the following cases H S T ?
Assertion: The extensive properties of a single pure substance will not only depend upon the number of moles of the substance present but also on any two of the three variables. Reason: Any extensive property if expre…
Assertion: There is no change in internal energy for an ideal gas at constant temperature. Reason: Internal energy of an ideal gas is a function of temperature only.
Bond dissociation energy of CH₄ is 360 kJ/mol and C₂H₆ is 620 kJ/mol. Then bond dissociation energy of C – C bond is
Find rH at 320 K for the reaction is:
The heat liberated when 1.89g of benzoic acid is burnt in a bomb calorimeter at 25 °C and it increases the temperature of 18.94 kg of water by 0.632 °C. if the specific heat of water at 25 °C is 0.998 cal/g- °C, the v…
Match List I with List II and select the correct answer using the codes given below the lists: List – I List – II A. T G P
Consider the reaction below at 298 K: C (graphite) + 2H₂ (g) → CH₄ (g) →fHº (kJ/mol) – 74.9 S₀ m(J/K/mol + 5.6 + 130.7 Which statement below is correct ?
In an isobaric process, when temperature changes from 1T to T , S is equal to
What is the entropy change in 2 mol N₂, when its temperature is taken from 400 K to 800 K. at constant pressure?
If one monoatomic gas is expanded adiabatically from 2L to 10L at 1 atm external pressure then the value of U (in atm L) is
Assertion: In isothermal process, whole of heat energy supplied to the system is converted into internal energy. Reason: According to the first law of thermodynamics U = q - w
A diatomic gas at pressure P, compressed adiabatically to half of its volume, what is the final pressure?
The magnitudes of enthalpy changes for irreversible adiabatic expansion of a gas from 1L to 2L is H₁ and for reversible adiabatic expansion for the same expansion is H₂. Then