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MEDIUMMCQ SINGLENEET ChemistryOrganic ChemistryAldehydes and ketones

The oxidation product of 2-propanol with hot conc. HNO3 is

MEDIUMMCQ SINGLENEET ChemistryOrganic ChemistryAldehydes and ketones

Oxidation reactions can be carried out with chromic acid in aqueous acetone at 5–10°C.Which of following is incorrect in this respect (a) (b)

MEDIUMMCQ SINGLENEET ChemistryOrganic ChemistryAldehydes and ketones

An organic compound X on treatment with pyridinium chloro chromate in dichloromethane gives compound Y. Compound Y reacts with I2 and alkali to form triiodomethane. The compound ‘X’ is

MEDIUMMCQ SINGLENEET ChemistryOrganic ChemistryAldehydes and ketones

Reduction of acetonitrile in presence of SnCl2/HCl, followed by hydrolysis gives :

MEDIUMMCQ SINGLENEET ChemistryOrganic ChemistryAldehydes and ketones

The reagent used in Gattermann Koch aldehyde synthesis is

MEDIUMMCQ SINGLENEET ChemistryOrganic ChemistryAldehydes and ketones

Arrange the following compounds in increasing order of their reactivity in nucleophilic addition reactions. Ethanal (I), Propanal (II), Propanone (III), Butanone (IV)

MEDIUMMCQ SINGLENEET ChemistryOrganic ChemistryAldehydes and ketones

A carbonyl compound reacts with hydrogen cyanide to form cyanohydrin which on hydrolysis forms a racemic mixture of a α-hydroxy acid. The carbonyl compound is

MEDIUMMCQ SINGLENEET ChemistryOrganic ChemistryAldehydes and ketones

The increasing order of the rate of HCN addition to compounds A-D is

MEDIUMMCQ SINGLENEET ChemistryOrganic ChemistryAldehydes and ketones

Nucleophilic addition reaction will be most favoured in

MEDIUMMCQ SINGLENEET ChemistryOrganic ChemistryAldehydes and ketones

Which of the aldehyde is most reactive towards nucleophilic addition reaction ?

MEDIUMMCQ SINGLENEET ChemistryOrganic ChemistryAldehydes and ketones

Product may be

MEDIUMMCQ SINGLENEET ChemistryOrganic ChemistryAldehydes and ketones

Which of the following carbonyl oxygen will form strongest hydrogen bond with 퐻2푂 molecule? (a) (b) (c) (d)

MEDIUMMCQ SINGLENEET ChemistryOrganic ChemistryAldehydes and ketones

Correct order of reactivity of CH3CHO, C2H5COCH3 and CH3COCH3 is

MEDIUMMCQ SINGLENEET ChemistryOrganic ChemistryAldehydes and ketones

The most reactive compound towards formation of cyanohydrin on treatment with HCN followed by acidification is

MEDIUMMCQ SINGLENEET ChemistryOrganic ChemistryAldehydes and ketones

A and B in the following reactions are (a) (b) (c)

MEDIUMMCQ SINGLENEET ChemistryOrganic ChemistryAldehydes and ketones

Reaction of acetaldehyde with HCN followed by hydrolysis gives a compound which shows

MEDIUMMCQ SINGLENEET ChemistryOrganic ChemistryAldehydes and ketones

Which one of the following does not form sodium bisulphite addition product with sodium bisulphite solution

MEDIUMMCQ SINGLENEET ChemistryOrganic ChemistryAldehydes and ketones

Benzaldehyde condenses with N,N-dimethylaniline in presence of anhydrous ZnCl2 to give

MEDIUMMCQ SINGLENEET ChemistryOrganic ChemistryAldehydes and ketones

Which of the following species is the conjugate acid of the hemiacetal formed by reaction of benzaldehyde with methanol containing a trace of acid ? (a) (b) (c) (d)

MEDIUMMCQ SINGLENEET ChemistryOrganic ChemistryAldehydes and ketones

Grignard reagent on reaction with acetone forms

MEDIUMMCQ SINGLENEET ChemistryOrganic ChemistryAldehydes and ketones

Product in following reaction is CH3MgI + HCHO → Product

MEDIUMMCQ SINGLENEET ChemistryOrganic ChemistryAldehydes and ketones

Identify the reactant X and the product Y

MEDIUMMCQ SINGLENEET ChemistryOrganic ChemistryAldehydes and ketones

The order of reactivity of phenyl magnesium bromide with the following compounds is

MEDIUMMCQ SINGLENEET ChemistryOrganic ChemistryAldehydes and ketones

Which of the following reagents converts both acetaldehyde and acetone to alkanes?

MEDIUMMCQ SINGLENEET ChemistryOrganic ChemistryAldehydes and ketones

Clemmensen reduction involves > C = O to > CH2 in presence of

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