MEDIUMMCQ SINGLENEET ChemistryOrganic ChemistryAldehydes and ketonesChemical Reactions of Carbonyl compounds

Correct order of reactivity of CH3CHO, C2H5COCH3 and CH3COCH3 is

A.CH3CHO > CH3COCH3>CH3COC2H5✓ Correct
B.C2H5COCH3> CH3COCH3> CH3CHO
C.CH3COCH3> CH3CHO > C2H5COCH3
D.CH3COCH3> C2H5COCH3> CH3CHO
Explanation

Both the aldehydes and ketones are very reactive towards the Nucleophilic addition reaction, because carbonyl group is a very reactive group. So, the reactivity of the carbonyl group can be decided the magnitude of the positive charge on the carbonyl group. So, the compounds that have least +I effect and stearic hinderance group will have the highest positive charge and will have highest reactivity. So, the order will be: 퐶퐻3퐶퐻푂> 퐶퐻3퐶푂퐶퐻3 > 퐶퐻3퐶푂퐶2퐻5. Aldehydes and Ketones 10

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