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MEDIUMMCQ SINGLENEET ChemistryInorganic ChemistryCoordination compounds

Which of the following octahedral complex ions is diamagnetic?

MEDIUMMCQ SINGLENEET ChemistryInorganic ChemistryCoordination compounds

Which of the following complex ions is diamagnetic?

MEDIUMMCQ SINGLENEET ChemistryInorganic ChemistryCoordination compounds

Which of the following complex ions is paramagnetic?

MEDIUMMCQ SINGLENEET ChemistryInorganic ChemistryCoordination compounds

The structures of Ni(CO)4 and Ni(PPh3)2Cl2 are

MEDIUMMCQ SINGLENEET ChemistryInorganic ChemistryCoordination compounds

Which of the following statements is correct?

MEDIUMMCQ SINGLENEET ChemistryInorganic ChemistryCoordination compounds

The formation of the complex ion [Co(NH3)6]3+ involves sp3d2 hybridization of Co3+. Hence, the complex ion should possess

MEDIUMMCQ SINGLENEET ChemistryInorganic ChemistryCoordination compounds

The hybridization states of the central atom in the complex ions [FeF6]3–, [Fe(H2O)6]3+ and [Ni(NH3)6]2+ are

MEDIUMMCQ SINGLENEET ChemistryInorganic ChemistryCoordination compounds

The hybridization states of the central atom in the complexes Fe(CN)6 3–, Fe(CN)6 4– and CO(NO2)6 3– are

MEDIUMMCQ SINGLENEET ChemistryInorganic ChemistryCoordination compounds

Which one of the following has a square planar geometry? (At. no. Co = 27, Ni = 28, Fe = 26, Pt = 78)

MEDIUMMCQ SINGLENEET ChemistryInorganic ChemistryCoordination compounds

The magnetic moment of a complex ion is 2.83 BM. The complex ion is

MEDIUMMCQ SINGLENEET ChemistryInorganic ChemistryCoordination compounds

The value of magnetic moment for a complex ion is 1.73 BM. The complex. ion is

MEDIUMMCQ SINGLENEET ChemistryInorganic ChemistryCoordination compounds

Among the following ions, which one has the highest paramagnetism?

MEDIUMMCQ SINGLENEET ChemistryInorganic ChemistryCoordination compounds

An octahedral complex is formed when hybrid orbitals or the following type are involved

MEDIUMMCQ SINGLENEET ChemistryInorganic ChemistryCoordination compounds

Which of the following complex ions obeys Sidgwick‘s effective atomic number (EAN) rule?

MEDIUMMCQ SINGLENEET ChemistryInorganic ChemistryCoordination compounds

The effective atomic number for the complex ion [Pd(NH3)6]4+ is

MEDIUMMCQ SINGLENEET ChemistryInorganic ChemistryCoordination compounds

The effective atomic number for the complex ion [Ni(CN)4]2– is

MEDIUMMCQ SINGLENEET ChemistryInorganic ChemistryCoordination compounds

Which of the following ion does not follow EAN rule?

MEDIUMMCQ SINGLENEET ChemistryInorganic ChemistryCoordination compounds

Mn H O 25–2 12 . Thus it violates EAN rule. Pt NH Fe CN 78 – 4 12 24+0 12 Fe CO 26+ 0 10

MEDIUMMCQ SINGLENEET ChemistryInorganic ChemistryCoordination compounds

Which of the following complex ions violates the EAN rule?

MEDIUMMCQ SINGLENEET ChemistryInorganic ChemistryCoordination compounds

Consider the following statements: According the Werner‘s theory. 1. Ligands are connected to the metal ions by covalent bonds. 2. Secondary valencies have directional properties 3. Secondary valencies are non-ionisab…

MEDIUMMCQ SINGLENEET ChemistryInorganic ChemistryCoordination compounds

In the complex with formula MCl3. 4H2O, the coordination number of the metal M is six and there is no molecule of hydration in it. The volume, if 0.1 M AgNO3 solution needed to precipitate the free chloride ions in 20…

MEDIUMMCQ SINGLENEET ChemistryInorganic ChemistryCoordination compounds

On treatment of 100 mL of 0.1 M solution of CoCl3.6H2O with excess of AgNO3; 1.2 × 1022 ions are precipitated. The complex is

MEDIUMMCQ SINGLENEET ChemistryInorganic ChemistryCoordination compounds

A coordination complex compound of cobalt has the molecular formula containing five ammonia molecules, one nitro group and two chlorine atoms for one cobalt atom. One mole of this compound produces three mole ions in …

MEDIUMMCQ SINGLENEET ChemistryInorganic ChemistryCoordination compounds

Excess of silver nitrate solution is added to 100 mL of 0.01 M pentaaquachlorochromium (III) chloride solution. The mass of silver chloride obtained (in gram) is [Atomic mass of silver is 108]

MEDIUMMCQ SINGLENEET ChemistryInorganic ChemistryCoordination compounds

Mixture X = 0.02 mole of [Co (NH3)5 SO4] Br and 0.02 mole of [Co(NH3)5 Br] SO4 was prepared in 2L of solution. 1 L of mixture X + excess AgNO3-> Y 1 L of mixture X + excess BaCl2-> Z Number of moles of Y and Z are

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