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HARDMCQ SINGLEJEE Mains ChemistryInorganic ChemistryCoordination compounds

The optically active coordination complex ion among the following is

HARDMCQ SINGLEJEE Mains ChemistryInorganic ChemistryCoordination compounds

Which of the following does not show optical isomerism? (en = ethylenediammine)

HARDMCQ SINGLEJEE Mains ChemistryInorganic ChemistryCoordination compounds

Which of the following complex species is not expected to exhibit optical isomerism?

HARDMCQ SINGLEJEE Mains ChemistryInorganic ChemistryCoordination compounds

The total number of possible isomers of the complex compound [CuII(NH₃)₄][PtIICl₄] is

HARDMCQ SINGLEJEE Mains ChemistryInorganic ChemistryCoordination compounds

The number of geometric isomers that can exist for square planar [Pt (Cl) (py) (NH₃) (NH₂OH)]+ is (py = pyridine):

HARDMCQ SINGLEJEE Mains ChemistryInorganic ChemistryCoordination compounds

The IUPAC name for [Pt(py)₄] [PtCl₄] is

HARDMCQ SINGLEJEE Mains ChemistryInorganic ChemistryCoordination compounds

The IUPAC name for [(CO)₃Fe(CO)₃ Fe(CO)₃] is

HARDMCQ SINGLEJEE Mains ChemistryInorganic ChemistryCoordination compounds

The IUPAC name for [(NH₃)₅ Cr– (OH) – Cr(NH₃)₅]5+ is a -hydroxo-bis (pentaammine dichromium) (5+) ion b -hydroxo-bis (decaamminedichromium) (5+) ion

HARDMCQ SINGLEJEE Mains ChemistryInorganic ChemistryCoordination compounds

Which among the following will be named as dibromidobis-(ethylenediamine) chromium (III) bromide?

HARDMCQ SINGLEJEE Mains ChemistryInorganic ChemistryCoordination compounds

Among the ligands NH₃, en, CN– and CO, the correct order of their increasing field strength, is

HARDMCQ SINGLEJEE Mains ChemistryInorganic ChemistryCoordination compounds

Among the following which are ambidentate ligands? (i) - NO (ii) - NO (iii) EDTA 4– (iv) C₂O₄ 2– (v) SCN –

HARDMCQ SINGLEJEE Mains ChemistryInorganic ChemistryCoordination compounds

The octahedral complex of a metal ion M3+ with four monodentate ligands L1, L2, L3 and L4 absorb wavelengths in the region of red, green, yellow and blue, respectively. The increasing order of ligand strength of the f…

HARDMCQ SINGLEJEE Mains ChemistryInorganic ChemistryCoordination compounds

Ammonia gas does not evolve from the complex FeCl₃.4NH₃ but it gives white precipitate with aqueous solution of AgNO₃. Coordination number of central metal ion in the above complex is six. Give IUPAC name of the complex

HARDMCQ SINGLEJEE Mains ChemistryPhysical ChemistryChemical kinetics

For a certain reaction A → products, the t1/2 as a function of [A]0 is given as below: [A]0 (M) : 0.1 0.025 t1/2 (min) : 100 Which of the following is/are true ?

HARDMCQ SINGLEJEE Mains ChemistryPhysical ChemistryChemical kinetics

The initial rates of reaction 3A + 2B + C → Products, at different initial concentrations are given below: Initial rate M s–1 [A]0 , M [B]0 , M [C]0 , M 5.0 × 10–3 0.010 0.005 0.010 5.0 × 10–3 0.010 0.005 0.015 1.0 × …

HARDMCQ SINGLEJEE Mains ChemistryPhysical ChemistryChemical kinetics

The hypothetical reaction A B 2AB; → follows the following mechanism Fast A A A, → Slow Fast A B AB B,A B AB. → → The order of the overall reaction is

HARDMCQ SINGLEJEE Mains ChemistryPhysical ChemistryChemical kinetics

The reaction of hydrogen and iodine monochloride is given as: H g 2ICl g 2HCl g I g → The reaction is of first order with respect to H₂ (g) and ICl(g), following mechanisms were proposed. Mechanism A: H g 2ICl g 2HCl …

HARDMCQ SINGLEJEE Mains ChemistryPhysical ChemistryChemical kinetics

With passage of time, the concentration of reactants …A… and rate of reaction …B… . Here A and B are

HARDMCQ SINGLEJEE Mains ChemistryPhysical ChemistryChemical kinetics

In most cases, for a rise of 10K temperature the rate constant is doubled to tripled. This is due to the reason that (a)collision frequency increases by a factor of 2 to 3. (b)fraction of molecules possessing threshol…

HARDMCQ SINGLEJEE Mains ChemistryPhysical ChemistryChemical kinetics

Collision theory is used to explain how chemical species undergo a reaction. Using this theory and the kinetic molecular model, which of the following does NOT influence the rate of a chemical reaction?

HARDMCQ SINGLEJEE Mains ChemistryPhysical ChemistryChemical kinetics

Choose the correct answer out of the following choices. Assertion (A): Most people think diamond is forever. Reason (R): Conversion rate of diamond to graphite is very low.

HARDMCQ SINGLEJEE Mains ChemistryPhysical ChemistryChemical kinetics

Assertion (A): In rate law, unlike in the expression for equilibrium constants, the exponents for concentrations do not necessarily match the stoichiometric coefficients. Reason (R): It is the mechanism and not the ba…

HARDMCQ SINGLEJEE Mains ChemistryPhysical ChemistryChemical kinetics

For the reaction 4 A B C D → , which of the following statement is not correct ?

HARDMCQ SINGLEJEE Mains ChemistryPhysical ChemistryChemical kinetics

Select the rate law that corresponds to the data shown for the following reaction A B C → Expt. (A) (B) Initial rate 0.012 0.035 0.10 0.024 0.070 0.80 0.024 0.035 0.10 0.012 0.070 0.80

HARDMCQ SINGLEJEE Mains ChemistryPhysical ChemistryChemical kinetics

For the following reaction: NO₂(g) + CO(g) → NO(g) + CO₂(g), the rate law is: Rate = k [NO₂]2.If 0.1 mole of gaseous carbon monoxide is added at constant temperature to the reaction mixture which of the following stat…

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