19,000+ solved questions for JEE Advanced, JEE Mains, NEET & IChO — with answers and expert explanations.
Assertion: pH of 10–8 M HCl lies between 6 and 7. Reason: For very dilute solutions of acids, H⁺ ion contribution from water is also taken into consideration.
Assertion: pH of water increases with an increase in temperature. Reason: Kw of water increases with increase in temperature.
Assertion: Addition of HCl(aq.) to HCOOH(aq.) decreases the ionization of HCOOH. Reason: Common ion effect of H⁺ ion, reduces the ionization of HCOOH.
Assertion (A): H₂SO₄ acts as a base in the presence of HClO₄. Reason (R): Perchloric acid is stronger acid than H₂SO₄.
The solubility products of MA, MB, MC and MD are 1.8 × 10–10, 4 × 10–3, 4 × 10–8 and 6 × 10–5 respectively. If a 0.01 M solution of MX is added dropwise to a mixture containing A–, B–, C– and D– ions then t…
Ksp of Mg (OH)₂ is 1 × 10–12. 0.01 M Mg (OH)₂ will be precipitating at the limiting pH :
Calculate the concentration of H⁺ ion in mol/L of 0.010M solution of NH₄Cl? (Kb = 1.8 × 10–6)
The correct order of increasing [H₃O⁺] in the following aqueous solution is:
H S aq H aq HS aq ;K 9.5 10 x HS aq H aq S aq ;K 1.0 10 x Given the equilibrium constants provided what is the equilibrium constant for the reaction: S (aq) 2H (aq) H S(aq) K = ?
How many milliliters (mL) of a 0.0500 M NaOH (a strong base) solution should be added to 1.00 L of 0.100 M H₃PO₄, solution to produce a buffer of pH = 2.00 ? For H₃PO₄, a K = 6.67 × 10–3 Given: H PO …
How many milliliters of 0.250 M NH₄Cl would have to be added to 450 mL of 0.350 M KOH in order to produce a buffer solution with a pH of 9.10? (Kb(NH₃) = 1.8 × 10–5)
Which pair of reagents, mixed in the appropriate proportion, could make a buffer in pH 3-4 range ?
A buffer is prepared by adding 0.30 mol CH₃COONa to 2.0 L of a 0.10 M CH₃COOH solution. Calculate the eq K /c (x y) eq K c/(xy) 1/(x y) x y 1 x y eq K /c x y eq K /xyc pH after 0.030 mol HCl are added t…
The pH of 10–5 M HCl solution if 1 ml of it is diluted to 1000 ml is :
When one drop of a concentrated HCl is added to 1 L of pure water at 25ºC, the pH drops suddenly from 7 to 4. When the second drop of the same acid is added, the pH of the solution further drops to about
A student dissolved 0.100 mol of an unknown monoprotic acid, HA, in sufficient water to make 1.00 L of solution. She measured the pH of the solution as pH = 2.60. Of the following, the acid HA is
For a “c molar” concentrated solution of a weak electrolyte AxBy, the degree of dissociation is given as (a) (b) (c) (d)
During hydrate formation from aqueous solution, water can be associated in different forms. Indicate the wrong combination. (i) Coordinated water – [Cr(H₂O)₆]3+ 3Cl– (ii) Interstitial water – BaCl₂.2H₂O (iii) Hydrogen…
Match the reaction of column I with their types given in column II and mark the appropriate choice. Column I Column II (A) H O NH NH OH (i) Self ionisation of H₂O (B) FeCl 3H O → Fe(OH) 3HCl (ii) Decomposition (C) H O…
Which of the statements given below are true for the water molecule structure? (i) Oxygen undergoes sp3hybridisation. (ii) Due to presence of two lone pairs of electrons on oxygen the H–O–H bonds angle is 118.4°. (iii…
Phosphorus cannot form PH₅ with its outer electronic configuration as 3s2, 3p3 because
Match the column I with column II and mark the appropriate choice. Column I Column II (A) NaH (i) Interstitial hydride (B) CH₄ (ii) Molecular hydride (C) VH₀.56 (iii) Ionic hydride (D) B₂H₆ (iv) Electron-deficient hyd…
A metal (M) produces a gas (N) on reaction with alkalis like NaOH and KOH. Same gas is produced when the metals react with dilute sulphuric acid. Gas (N) reacts with another toxic gas (P) to form methanol at high temp…
Which of the following reaction produces hydrogen?
Consider the following statements: 1. Atomic hydrogen is obtained by passing hydrogen through an electric arc. 2. Hydrogen gas will not reduce heated aluminium oxide. 3. Finely divided palladium absorbs large volume o…