19,000+ solved questions for JEE Advanced, JEE Mains, NEET & IChO — with answers and expert explanations.
One mole of an ideal gas expands reversibly and adiabatically from a temperature of 27°C. If the work done during the process is 3 kJ, then final temperature of the gas is:(CV = 20 J/K)
Which one of the following has S greater than zero? (a) CaO s CO g CaCO s (b) NaCl aq NaCl s (c) NaNO s Na aq NO aq (d) N g 3H g 2NH g
G T S when H
G H T S when H S Hence, Correct option is c
Unit of entropy is
In which case change in entropy is negative?
One mole of an ideal diatomic gas (Cv = 5 cal) was transformed from initial 25°C and 1 L to the state when temperature is 100°C and volume 10 L. The entropy change of the process can be expressed as (R = 2 calories/mo…
A reaction has ∆H = – 33 kJ and ∆S = +58 J/K. This reaction would be :
Pick out the wrong statement
For the gas phase reaction, PCl g PCl g Cl g Which of the following conditions are correct?
Enthalpy change for the reaction, 4H(g) → 2H₂(g) is – 869.5 kJ. The dissociation energy of H–H bond is
Which of the following reactions define o f G ? (a) diamond C O g CO g → (b) H g F g HF g → (c) H P O H O 2H PO → (d) SO g O g SO g →
The enthalpy of vaporisation of a compound AB at its boiling point (127°C) is 6.4 kJ mol-1. Its entropy of vaporization is
The following data is known about the melting of a compound AB. ∆H = 9.2 kJ mol–1. ∆S = 0.008 kJ K–1mol–1. Its melting point is :
∆H for the reaction, SO g O g SO g ∆H = –98.3 kJ If the enthalpy of formation of SO₃(g) is –395.4 kJ then the enthalpy of formation of SO₂(g) is :
When 0.5 g of sulphur is burnt to SO₂ 4.6 kJ of heat is liberated. What is the enthalpy of formation of sulphurdioxide?
105. (∆U – ∆H) for the formation of NH₃ from N₂ and H₂ is :
H for the reaction, C(graphite) 2H (g) CH (g) → at 298 K and 1 atm is – 17900 cal. The E for the above conversion would be
If the bond energies of H–H, Br–Br, and H–Br are 433, 192 and 364 kJ mol–1 respectively, the H for the reaction 2(g) 2(g) (g) H Br 2HBr → is (2004)
The densities of graphite and diamond at 298 K are 2.25 and 3.31 g cm–3, respectively. The standard free energy difference ( G ) is equal to 1895 J mol–1, the pressure at which graphite will be transformed into diamon…
A reaction occurs spontaneously if (2005)
Assume each reaction is carried out in an open container. For which reaction will H = E ? (CBSE AIPMT 2006) (a) H (g) Br (g) 2HBr(g) → (b) C(s) 2H O(g) 2H (g) CO (g) → (c) PCl (g) PCl (g) Cl (g) → (d) 2CO(g) O (g) 2CO…
Consider the following reaction –1 (aq) (aq) (l) –1 2(g) 2(g) (l) 2(g) 2(g) (g) (l) –1 2(g) 2(g) 2(g) (l) –1 (i)H OH H O , H X kJ mol (ii)H 1/ 2O H O , H X kJ mol (iii)CO H CO H O , H X kJ mol (iv)C H 5 / 2O 2CO H O ,…
Given that bond energies of H – H and Cl – Cl are 430 kJ mol–1 and 240 kJ mol–1 respectively and f H for HCl is-90 kJ mol–1 bond enthalpy of HCl is (2007)
The following two reactions are known Fe₂O₃(s) + 3CO(g) → 2Fe(s) + 3CO₂(g); ∆H = –26.8 kJ FeO(s) + CO(g) → Fe(s) + CO₂(g); ∆H = – 16.5 kJ The value of ∆H for the following reaction Fe₂O₃(s) + CO(g) → 2FeO(s) + CO₂(g) …