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MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryThermodynamics and Thermochemistry

One mole of an ideal gas expands reversibly and adiabatically from a temperature of 27°C. If the work done during the process is 3 kJ, then final temperature of the gas is:(CV = 20 J/K)

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryThermodynamics and Thermochemistry

Which one of the following has  S  greater than zero? (a) CaO s CO g CaCO s (b) NaCl aq NaCl s (c) NaNO s Na aq NO aq (d) N g 3H g 2NH g

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryThermodynamics and Thermochemistry

G T S  when H

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryThermodynamics and Thermochemistry

G H T S when H S Hence, Correct option is c

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryThermodynamics and Thermochemistry

Unit of entropy is

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryThermodynamics and Thermochemistry

In which case change in entropy is negative?

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryThermodynamics and Thermochemistry

One mole of an ideal diatomic gas (Cv = 5 cal) was transformed from initial 25°C and 1 L to the state when temperature is 100°C and volume 10 L. The entropy change of the process can be expressed as (R = 2 calories/mo…

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryThermodynamics and Thermochemistry

A reaction has ∆H = – 33 kJ and ∆S = +58 J/K. This reaction would be :

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryThermodynamics and Thermochemistry

Pick out the wrong statement

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryThermodynamics and Thermochemistry

For the gas phase reaction, PCl g PCl g Cl g Which of the following conditions are correct?

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryThermodynamics and Thermochemistry

Enthalpy change for the reaction, 4H(g)  → 2H₂(g) is – 869.5 kJ. The dissociation energy of H–H bond is

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryThermodynamics and Thermochemistry

Which of the following reactions define o f G ? (a) diamond C O g CO g → (b) H g F g HF g → (c) H P O H O 2H PO → (d) SO g O g SO g →

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryThermodynamics and Thermochemistry

The enthalpy of vaporisation of a compound AB at its boiling point (127°C) is 6.4 kJ mol-1. Its entropy of vaporization is

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryThermodynamics and Thermochemistry

The following data is known about the melting of a compound AB. ∆H = 9.2 kJ mol–1. ∆S = 0.008 kJ K–1mol–1. Its melting point is :

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryThermodynamics and Thermochemistry

∆H for the reaction, SO g O g SO g ∆H = –98.3 kJ If the enthalpy of formation of SO₃(g) is –395.4 kJ then the enthalpy of formation of SO₂(g) is :

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryThermodynamics and Thermochemistry

When 0.5 g of sulphur is burnt to SO₂ 4.6 kJ of heat is liberated. What is the enthalpy of formation of sulphurdioxide?

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryThermodynamics and Thermochemistry

105. (∆U – ∆H) for the formation of NH₃ from N₂ and H₂ is :

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryThermodynamics and Thermochemistry

H for the reaction, C(graphite) 2H (g) CH (g) → at 298 K and 1 atm is – 17900 cal.  The E for the above conversion would be

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryThermodynamics and Thermochemistry

If the bond energies of H–H, Br–Br, and H–Br are 433, 192 and 364 kJ mol–1 respectively, the H for the reaction 2(g) 2(g) (g) H Br 2HBr → is (2004)

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryThermodynamics and Thermochemistry

The densities of graphite and diamond at 298 K are 2.25 and 3.31 g cm–3, respectively. The standard free energy difference ( G ) is equal to 1895 J mol–1, the pressure at which graphite will be transformed into diamon…

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryThermodynamics and Thermochemistry

A reaction occurs spontaneously if (2005)

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryThermodynamics and Thermochemistry

Assume each reaction is carried out in an open container. For which reaction will H = E ? (CBSE AIPMT 2006) (a) H (g) Br (g) 2HBr(g) → (b) C(s) 2H O(g) 2H (g) CO (g) → (c) PCl (g) PCl (g) Cl (g) → (d) 2CO(g) O (g) 2CO…

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryThermodynamics and Thermochemistry

Consider the following reaction –1 (aq) (aq) (l) –1 2(g) 2(g) (l) 2(g) 2(g) (g) (l) –1 2(g) 2(g) 2(g) (l) –1 (i)H OH H O , H X kJ mol (ii)H 1/ 2O H O , H X kJ mol (iii)CO H CO H O , H X kJ mol (iv)C H 5 / 2O 2CO H O ,…

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryThermodynamics and Thermochemistry

Given that bond energies of H – H and Cl – Cl are 430 kJ mol–1 and 240 kJ mol–1 respectively and f H for HCl is-90 kJ mol–1 bond enthalpy of HCl is (2007)

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryThermodynamics and Thermochemistry

The following two reactions are known Fe₂O₃(s) + 3CO(g) → 2Fe(s) + 3CO₂(g); ∆H = –26.8 kJ FeO(s) + CO(g) → Fe(s) + CO₂(g); ∆H = – 16.5 kJ The value of ∆H for the following reaction Fe₂O₃(s) + CO(g) → 2FeO(s) + CO₂(g) …

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