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HARDMCQ SINGLEJEE Advanced ChemistryInorganic ChemistryCarboxylic Acids and Derivatives

(a) (b) Carboxylic Acid and Its Derivatives (c) (d)

HARDMCQ SINGLEJEE Advanced ChemistryInorganic ChemistryCarboxylic Acids and Derivatives

An enantiomerically pure acid is treated with racemic mixture of an alcohol having one chiral carbon. The ester formed will be

HARDMCQ SINGLEJEE Advanced ChemistryInorganic ChemistryCarboxylic Acids and Derivatives

The strongest acid among the following is –

HARDMCQ SINGLEJEE Advanced ChemistryInorganic ChemistryCarboxylic Acids and Derivatives

Assertion : Acid catalysed hydrolysis of ester is reversible on the other hand base catalysed hydrolysis is irreversible. Reason : In acid catalysed ester hydrolysis carboxylic acid is formed on which nucleophile atta…

HARDMCQ SINGLEJEE Advanced ChemistryInorganic ChemistryCarboxylic Acids and Derivatives

Ethyl isocyanide on hydrolysis in acidic medium generates

HARDMCQ SINGLEJEE Advanced ChemistryInorganic ChemistryCarboxylic Acids and Derivatives

The end product B in the sequence of reactions, Carboxylic Acid and Its Derivatives CN NaOH R X A B → → is

HARDMCQ SINGLEJEE Advanced ChemistryInorganic ChemistryCarboxylic Acids and Derivatives

Assertion:Formic acid reduces mercuric chloride. Reason: Formic acid is stronger than acetic acid.

HARDMCQ SINGLEJEE Advanced ChemistryInorganic ChemistryCarboxylic Acids and Derivatives

Assertion : Acetic acid does not give haloform reaction. Reason : Acetic acid has no -hydrogen.

HARDMCQ SINGLEJEE Advanced ChemistryInorganic ChemistryCarboxylic Acids and Derivatives

Assertion : (CH₃)₃C–COOH does not give HVZ reaction. Reason : It does not have any -hydrogen

HARDMCQ SINGLEJEE Advanced ChemistryInorganic ChemistryCarboxylic Acids and Derivatives

Assertion : p–hydroxybenzoic acid has a lower boiling point than o–hydroxybenzoic acid. Reason : o–hydroxybenzoic acid has intramolecular hydrogen bonding.

HARDMCQ SINGLEJEE Advanced ChemistryInorganic ChemistryCarboxylic Acids and Derivatives

In the given reaction, H O C H CO O I → H O C H COOCOCH II → Identify the product(s) formed in the given reaction. I II

HARDMCQ SINGLEJEE Advanced ChemistryOrganic ChemistryBiomolecules

Assertion (A) Glucose gives reddish brown precipitate with Fehling solution. Reason (R) Reaction of glucose with Fehling solution gives CuO and gluconic acid.

HARDMCQ SINGLEJEE Advanced ChemistryOrganic ChemistryBiomolecules

Assertion: Activity of an enzyme is pH-dependent. Reason: Change in pH affects the solubility of the enzyme in water.

HARDMCQ SINGLEJEE Advanced ChemistryOrganic ChemistryBiomolecules

Assertion: Alpha -amino acids exist as internal salt in solution as they have amino and carboxylic acid groups in near vicinity. Reason: H ion given by carboxylic group (– COOH) is captured by amino group (–NH₂) havin…

HARDMCQ SINGLEJEE Advanced ChemistryOrganic ChemistryBiomolecules

Assertion: Proteins on hydrolysis produce amino acids. Reason: Amino acids contain –NH₂ and –COOH groups.

HARDMCQ SINGLEJEE Advanced ChemistryOrganic ChemistryBiomolecules

Sucrose in water is dextrorotatory, []D = + 66.4° when boiled with dil. HCl, the solution becomes laevo-rotatory, []D = – 39.9°. In this process the sucrose breaks into

HARDMCQ SINGLEJEE Advanced ChemistryOrganic ChemistryBiomolecules

Glycolysis is

HARDMCQ SINGLEJEE Advanced ChemistryOrganic ChemistryBiomolecules

Which one of the following statements is true for protein synthesis (translation) ?

HARDMCQ SINGLEJEE Advanced ChemistryOrganic ChemistryBiomolecules

The pair in which both species have iron is

HARDMCQ SINGLEJEE Advanced ChemistryOrganic ChemistryBiomolecules

Which statement is incorrect about peptide bond?

HARDMCQ SINGLEJEE Advanced ChemistryOrganic ChemistryBiomolecules

Which functional group participates in disulphide bond formation in proteins ?

HARDMCQ SINGLEJEE Advanced ChemistryOrganic ChemistryBiomolecules

The human body does not produce

HARDMCQ SINGLEJEE Advanced ChemistryOrganic ChemistryBiomolecules

The cell membranes are mainly composed of

HARDMCQ SINGLEJEE Advanced ChemistryOrganic ChemistryBiomolecules

The hormone which controls the processes like burning of fats, proteins and carbohydrates to liberate energy in the body is

HARDMCQ SINGLEJEE Advanced ChemistryOrganic ChemistryBiomolecules

Assertion: DNA molecules and all RNA molecules are found in the nucleus of a cell. Reason: On heating, the enzymes do not lose their specific activity.

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