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MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryIonic equilibrium

Ka for HF is 3.5 × 10–4. Calculate Kb for the fluoride ion.

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryIonic equilibrium

HCN is  a weak  acid (Ka =  6.2 ×  10–10).  NH4OH  is a weak base (Kb = 1.8 × 10–5). A 1M solution of NH4CN would be :

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryIonic equilibrium

A physician wishes to prepare a buffer solution at pH = 3.58 that efficiently resists a change in pH yet contains only small conc. of the buffering agents. Which one of the following weak acid together with its sodium…

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryIonic equilibrium

The  pH  of  blood  does  not  appreciably  change  by  a small addition of acid or a base because blood

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryIonic equilibrium

How many moles of HCOONa must be added to 1L of 0.1 M HCOOH to prepare a buffer solution with a pH of  3.4  ?  (Given  :  Ka  for  HCOOH  =  2  ×  10 –4); (10-0.3 = 0.5)

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryIonic equilibrium

The dissociation constant of HCN is 5 × 10 –10. The pH of the solution prepared by mixing 1.5 mole of HCN and  0.15  moles  of  KCN  in  water  and  making  up the total volume to 0.5 dm 3 is

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryIonic equilibrium

In  a  mixture  of  a  weak  acid  and  its  salt, the  ratio  of concentration of acid to salt is increased ten-fold. The pH of the solution

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryIonic equilibrium

The  pKa  value  of  NH3  is  5.  Calculate  the  pH  of  the buffer solution, 1 L of which contains 0.01 M NH4Cl and 0.10 M NH4OH

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryIonic equilibrium

Consider the following solutions of equal concentrations. A = NH4Cl        B = CH3COONa C = NH4OH      D = CH3COOH A  buffer  solution  can  be  obtained  by  mixing  equal volumes of

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryIonic equilibrium

Which of the following pairs constitutes a buffer?

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryIonic equilibrium

Solution  of  0.1  N  NH4OH  and  0.1  N  NH4Cl  has  pH 9.25. The pKb of NH4OH is

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryIonic equilibrium

A certain buffer solution contains equal concentration  of  X–  and  HX.  the  Ka  for  HX  is  10–8. The pH of the buffer is

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryIonic equilibrium

One litre of a buffer solution containing 0.01 M NH4Cl and 0.1 M NH4OH having pKb of 5 has pH of

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryIonic equilibrium

A buffer solution of pH 9 can be prepared by mixing

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryIonic equilibrium

The acidic buffer solution can be prepared by mixing solutions of

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryIonic equilibrium

Buffer  solution  can  be  obtained  by  mixing  aqueous solution of

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryIonic equilibrium

A mixture of a weak acid (say acetic acid) and its salt with a strong base (say sodium acetate) is a buffer solution. Which other pair of substances from the following may have a similar property ?

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryIonic equilibrium

A certain buffer solution contains equal concentration of  Xand HX. The Kb for  X is 10–10. The pH of the buffer is

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryIonic equilibrium

Calculate the pH of a buffer prepared by mixing 0.10 mol of sodium formate and 0.05 mole of formic acid in 1.0 L of solution. [HCO2H : Ka =1.8 × 10–4]

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryIonic equilibrium

What is the pH of a buffer solution which is 0.250 M in benzoic  acid,  C6H5COOH,  and  0.150  M  in  sodium benzoate, C6H5COONa, if a K  for benzoic acid is 6.5 × 10–5 ?

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryIonic equilibrium

The principal buffer present in human blood is

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryIonic equilibrium

For  preparing  a  buffer  solution  of  pH  6  by  mixing sodium  acetate  and  acetic  acid,  the  ratio  of  the concentration of salt and acid should be (Ka = 10 –5)

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryIonic equilibrium

The pKb of  CNis 4.7. The pH of solution prepared by mixing 2.5 mol of KCN of 2.5 mol of HCN in water and making the total volume up to 500 mL is

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryIonic equilibrium

10–6 M NaOH is diluted by 100 times. The pH of diluted base is

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryIonic equilibrium

K C K /C x xx a H

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