19,000+ solved questions for JEE Advanced, JEE Mains, NEET & IChO — with answers and expert explanations.
Which thermodynamic parameter is not a state function?
A system undergoes a 2-step process. In step 1, 15 J of work is done on the system as its internal energy increases by a total of 30 J. In step 2, at constant volume, the system decreases its internal energy by 20 J. …
1 mole of an ideal gas expands isothermally reversibly from 2 litre to 4 litre and 3 moles of the same gas expands from 2 litre to x litre and doing same work, what is ‘x’?
If one monoatomic gas is expanded adiabatically from 2L to 10L at 1 atm external pressure then the value of U (in atm L) is
The magnitudes of enthalpy changes for irreversible adiabatic expansion of a gas from 1L to 2L is H₁ and for reversible adiabatic expansion for the same expansion is H₂. Then
When 1 mol of an ideal gas is compressed to half of its volume, its temperature becomes double; then the change in entropy (S) would be:
Consider the reaction below at 298 K: C (graphite) + 2H₂ (g) → CH₄ (g) →fHº (kJ/mol) – 74.9 S₀ m(J/K/mol + 5.6 + 130.7 Which statement below is correct ?
B. P G T 2. T C. P H S 3. -S D. H T P 4. P 5. V
Bond dissociation energy of CH₄ is 360 kJ/mol and C₂H₆ is 620 kJ/mol. Then bond dissociation energy of C – C bond is
Assertion: There is no change in internal energy for an ideal gas at constant temperature. Reason: Internal energy of an ideal gas is a function of temperature only.
Assertion: In isothermal process, whole of heat energy supplied to the system is converted into internal energy. Reason: According to the first law of thermodynamics U = q - w
The heat liberated when 1.89g of benzoic acid is burnt in a bomb calorimeter at 25 °C and it increases the temperature of 18.94 kg of water by 0.632 °C. if the specific heat of water at 25 °C is 0.998 cal/g- °C, the v…
Assertion: 1.575g H₂C₂O₄.2H₂O in 250 mL solution makes it 0.1 N. Reason : H₂C₂O₄.2H₂O is a dihydrate organic acid.
60 mL of N/5 H₂SO₄, 10 mL of N/2 HNO₃ and 30 mL of N/10 HCl are mixed together. The strength of the resulting mixture is (UP CPMT 2009)
Calculate the mass of urea (NH₂CONH₂) required in making 0.25 molal aqueous solution using 2.5 L water. (Haryana PMT 2010)
At o 25 C, the total pressure of an ideal solution obtained by mixing 3 moles of ‘A’ and 2 moles of ‘B’, is 184 torr. What is the vapour pressure (in torr) of pure ‘B’ at the same temperature? (Vapour pressure of pure…
0.2 molal acid HX ionises 20%. Kf for acid is 1.86 molality–1. Freezing point is
A solution contains non-volatile solute of molecular mass M2. Which of the following can be used to calculate the molecular mass of solute in terms of osmotic pressure? (Punjab PMET 2007) (a) m M VRT (b) m RT M V (c) …
25.3 g of sodium carbonate, Na₂CO₃ is dissolved in enough water to make 250 mL of solution. If sodium carbonate dissociates completely, molar concentration of sodium ion and carbonate ions respectively are (Molar mass…
0.01 M solution each of urea, common salt and Na₂SO₄ are taken, the ratio of depression of freezing point is
Van’t Hoff factor of Ca (NO₃)₂ is
If sodium sulphate is considered to be completely dissociated into cations and anions in aqueous solution, the change in freezing point of water ( Tf), when 0.01 mole of sodium sulphate is dissolved in 1 kg of water, …
Which of the following pair of solutions are expected to be isotonic at the same temperature?
Four solutions of K₂SO₄ with the following concentration 0.1 m, 0.01 m, 0.001 m and 0.0001 m SOLUTIONS are available. The maximum value of van’t Hoff factor, i, corresponds to
Which of the following aqueous solutions has the highest boiling point?