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MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryThermodynamics and Thermochemistry

The heat liberated when 1.89 g of benzoic acid is burnt in a bomb calorimeter at 25 °C increases the temperature of 18.94 kg of water by 0.632 °C. If the specific heat of water at 25 °C is 0.998 cal/g-deg, the value o…

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryThermodynamics and Thermochemistry

The following two reactions are known Fe₂O₃(s) + 3CO(g) → 2Fe(s) + 3CO₂(g); ∆H = –26.8 kJ FeO(s) + CO(g) → Fe(s) + CO₂(g); ∆H = – 16.5 kJ The value of ∆H for the following reaction Fe₂O₃(s) + CO(g) → 2FeO(s) + CO₂(g) …

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryThermodynamics and Thermochemistry

If the enthalpy change for the transition of liquid water to steam is 30 kJ mol–1 at 27°C, the entropy change for the process would be (2011)

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryThermodynamics and Thermochemistry

Standard enthalpy of vaporisation o vap H for water at 100°C is 40.66 kJ mol–1. The internal energy of vaporisation of water at 100°C (in kJ mol–1) is (2012)

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryThermodynamics and Thermochemistry

The enthalpy of fusion of water is 1.435 kcal/mol. The molar entropy change for the melting of ice at 0°C is (2012)

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryThermodynamics and Thermochemistry

Three thermochemical equations are given below: (i) C(graphite) + O₂(g) → CO₂(g); ∆rH° = x kJ mol–1 (ii) C(graphite) + ½O₂(g) → CO(g); ∆rH° = y kJ mol–1 (iii) CO(g) + ½O₂(g) → CO₂(g); ∆rH° = z kJ mol–1 Based on the ab…

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryThermodynamics and Thermochemistry

The heat of combustion of carbon to CO₂ is –393.5 kJ/mol. The heat released upon formation of 35.2 g of CO₂ from carbon and oxygen gas is (2015)

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryThermodynamics and Thermochemistry

For a sample of perfect gas when its pressure is changed isothermally from pi to pf, the entropy change is given by. (NEET-II 2016)

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryThermodynamics and Thermochemistry

A gas is allowed to expand in a well-insulated container against a constant external pressure of 2.5 atm from an initial volume of 2.50 L to a final volume of 4.50 L. The change in internal energy U of the gas in joul…

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryThermodynamics and Thermochemistry

For a given reaction, ∆H = 35.5 kJ mol–1 and ∆S = 83.6 J K–1 mol–1. The reaction is spontaneous at (Assume that ∆H and ∆S do not vary with temperature.) (NEET 2017)

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryThermodynamics and Thermochemistry

For the reaction, 2Cl(g) → Cl₂(g), the correct option is (NEET 2020)

HARDMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryThermodynamics and Thermochemistry

Which thermodynamic parameter is not a state function?

HARDMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryThermodynamics and Thermochemistry

A system undergoes a 2-step process. In step 1, 15 J of work is done on the system as its internal energy increases by a total of 30 J. In step 2, at constant volume, the system decreases its internal energy by 20 J. …

HARDMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryThermodynamics and Thermochemistry

1 mole of an ideal gas expands isothermally reversibly from 2 litre to 4 litre and 3 moles of the same gas expands from 2 litre to x litre and doing same work, what is ‘x’?

HARDINTEGERIChO (Chemistry Olympiad)Physical ChemistryThermodynamics and Thermochemistry

If one monoatomic gas is expanded adiabatically from 2L to 10L at 1 atm external pressure then the value of U (in atm L) is

HARDMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryThermodynamics and Thermochemistry

The magnitudes of enthalpy changes for irreversible adiabatic expansion of a gas from 1L to 2L is H₁ and for reversible adiabatic expansion for the same expansion is H₂. Then

HARDMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryThermodynamics and Thermochemistry

When 1 mol of an ideal gas is compressed to half of its volume, its temperature becomes double; then the change in entropy (S) would be:

HARDMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryThermodynamics and Thermochemistry

Consider the reaction below at 298 K: C (graphite) + 2H₂ (g) → CH₄ (g) →fHº (kJ/mol) – 74.9 S₀ m(J/K/mol + 5.6 + 130.7 Which statement below is correct ?

HARDMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryThermodynamics and Thermochemistry

B. P G T 2. T C. P H S 3. -S D. H T P 4. P 5. V

HARDMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryThermodynamics and Thermochemistry

Bond dissociation energy of CH₄ is 360 kJ/mol and C₂H₆ is 620 kJ/mol. Then bond dissociation energy of C – C bond is

HARDMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryThermodynamics and Thermochemistry

Assertion: There is no change in internal energy for an ideal gas at constant temperature. Reason: Internal energy of an ideal gas is a function of temperature only.

HARDMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryThermodynamics and Thermochemistry

Assertion: In isothermal process, whole of heat energy supplied to the system is converted into internal energy. Reason: According to the first law of thermodynamics U = q - w

HARDINTEGERIChO (Chemistry Olympiad)Physical ChemistryThermodynamics and Thermochemistry

The heat liberated when 1.89g of benzoic acid is burnt in a bomb calorimeter at 25 °C and it increases the temperature of 18.94 kg of water by 0.632 °C. if the specific heat of water at 25 °C is 0.998 cal/g- °C, the v…

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryThermodynamics and Thermochemistry

The state of a thermodynamic system is represented by

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryThermodynamics and Thermochemistry

Which of the following is true about isolated system?

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