Calculate value of "x y" for "hypophosphoric acid", where x is total number of lone pair(s) and y is β p Block Elements Chemistry Question
Question
Calculate value of "x $\div$ y" for "hypophosphoric acid", where x is total number of lone pair(s) and y is total number $\pi$-bond(s) in given oxo-acids.
Answer: 6 / STRUCTURE OF HYPOPHOSPHORIC ACID IS H4P2O6. X = 12 (LONE PAIRS), Y = 2 ($\PI$ BONDS). X $\DIV$ Y = 12 / 2 = 6
π‘ Solution & Explanation
Step 1: The reducing power of Group 15 hydrides (MH3) depends on the strength of the M-H bond (thermal stability). Step 2: As we move down the group from N to Sb, the size of the central atom increases, leading to a decrease in orbital overlap, which weakens the M-H bond and makes it easier to release hydrogen. Step 3: Since Sb-H is the weakest bond among the options, SbH3 is the strongest reducing agent, corresponding to option (d).
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