Colour of compounds occurs due to phenomenon of polarisation, charge transfer, d-d transition and H. β Chemical Bonding Chemistry Question
Question
Colour of compounds occurs due to phenomenon of polarisation, charge transfer, d-d transition and H.O.M.O.-L.U.M.O. transition. Most of the transition metal complex compound are coloured either due to d-d electron transition or charge transfer and ionic compounds are coloured due to polarisation of anion.
π‘ Solution & Explanation
Step 1: Understand that the potential energy of a bonding system reaches a minimum at the optimum internuclear distance (bond length), balancing attractions and repulsions. Step 2: If the internuclear distance is decreased below this optimum distance, the nuclei and core electron clouds are forced too close together. Step 3: This leads to a massive, steep increase in potential energy due to the sharp increase in electrostatic repulsions between the positively charged nuclei and between the negatively charged electron clouds.