'A' + H2O NaOH; 'A' B NaOH + O2<br>B is used for oxygenating in submarine. A and B are : β s Block Elements Chemistry Question
Question
'A' + H2O $\rightarrow$ NaOH; 'A' $\xrightarrow{\text{O}_2, 400^\circ\text{C}}$ B $\xrightarrow{\text{H}_2\text{O at } 25^\circ\text{C}}$ NaOH + O2<br>B is used for oxygenating in submarine. A and B are :
π‘ Solution & Explanation
Step 1: On a large scale, sodium hydroxide (caustic soda) is manufactured by the electrolysis of an aqueous solution of sodium chloride (brine) in a Castner-Kellner cell or membrane cell. Step 2: At the anode, chloride ions are oxidized to chlorine gas (2Cl- -> Cl2 + 2e-). At the cathode, water is reduced to hydrogen gas and hydroxide ions (2H2O + 2e- -> H2 + 2OH-), leaving sodium hydroxide in the solution. Step 3: This process is the electrolytic chlor-alkali process, corresponding to option (b).