Consider the following sequence of reactions : M^2+(aq.) --NH4Cl(s) + (NH4)2CO3 sol.--> Qβ --CH3COOH β Redox Reactions and Volumetric Analysis Chemistry Question
Question
Consider the following sequence of reactions : M^2+(aq.) --NH4Cl(s) + (NH4)2CO3 sol.--> Qβ --CH3COOH followed by addition of (NH4)2C2O4--> Rβ. Which of the following cation can form ppt. Q but does not form ppt. 'R' ?
π‘ Solution & Explanation
Step 1: Identify the reactants. Ferric cyanide, Fe(CN)3β, is an insoluble precipitate. Step 2: Analyze the complexation. The addition of potassium cyanide (KCN) provides excess cyanide ligands that coordinate with iron(III) to form the highly stable, soluble coordination complex potassium ferricyanide (K3[Fe(CN)6]). Step 3: Since the solid ferric cyanide precipitate dissolves to yield a clear soluble complex solution, this is a precipitate dissolution reaction (type B). Thus, the correct option is (b).