A doctor by mistake administers a Ba(NO3)2 solution to a patient for radiography investigations. Whi β Qualitative and Quantitative Analysis Chemistry Question
Question
A doctor by mistake administers a Ba(NO3)2 solution to a patient for radiography investigations. Which of the following should be given as the best to prevent the absorption of soluble barium?
π‘ Solution & Explanation
Step 1: Soluble barium salts like Ba(NO3)2 are highly toxic due to the physiological activity of free Ba2+ ions. Step 2: To prevent absorption in the digestive tract, the toxic Ba2+ ions must be precipitated as an extremely insoluble, non-toxic compound. Step 3: Adding sodium sulfate (Na2SO4) precipitates the barium as barium sulfate (BaSO4β), which is highly insoluble in gastric juices (Ksp ~ 1.1 x 10^-10) and safely excreted. This corresponds to option (b).