JEE Mains Chemistry Past PapershardNUMERICAL

The number of paramagnetic metal complex species among [Co(NH3)63+], [Co(C2O4)3]3–, [MnCl6]3–, [Mn(CJEE Mains Chemistry Past Papers Chemistry Question

Question

The number of paramagnetic metal complex species among [Co(NH3)63+], [Co(C2O4)3]3–, [MnCl6]3–, [Mn(CN)6]3– , [CoF6]3– and [FeF6]3– with same number of unpaired electrons is__________

Answer: .

💡 Solution & Explanation

[Co(NH3)6]3+ Co3+ 3d6 ,2 ,2 g 2t , g e Diamagnetic (unpaired electron = 0) [Co(C2O4)3]3– Co3+ 3d6 ,2 ,2 g 2t , g e Diamagnetic (unpaired electron = 0) [MnCl6]3– Mn3+ 3d4 ,1 ,1 g 2t ,1 g e Paramagnetic (unpaired electron = 4) [Mn(CN)6]3– Mn3+ 3d4 ,1 ,2 g 2t , g e Paramagnetic (unpaired electron = 2) [CoF6]3– Co3+ 3d6 ,1 ,2 g 2t ,1 g e Paramagnetic (unpaired electron = 4) [Fe(CN)6]3– Fe3+ 3d5 ,2 ,2 g 2t , g e Paramagnetic (unpaired electron = 1) [FeF6]3– Fe3+ 3d5 ,1 ,1 g 2t ,1 g e Paramagnetic (unpaired electron = 5)

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