Salt (A) gives brick red fumes (B) with conc. H2SO4 and K2Cr2O7 which gives yellow solution (C) with β Qualitative and Quantitative Analysis Chemistry Question
Question
Salt (A) gives brick red fumes (B) with conc. H2SO4 and K2Cr2O7 which gives yellow solution (C) with NaOH and it gives yellow ppt. (D) with acetic acid and lead acetate. What is (C)?
Answer: A
π‘ Solution & Explanation
Step 1: Heating a chloride salt like NaCl with conc. H2SO4 and K2Cr2O7 produces orange-red chromyl chloride (CrO2Cl2) vapours (B). Step 2: Passing CrO2Cl2 vapours into NaOH solution forms a yellow solution of sodium chromate (Na2CrO4) (C). Step 3: Therefore, the yellow solution (C) is Na2CrO4, which corresponds to option (a).
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