Ammonia forms the complex [Cu(NH3)4]^2+ with copper ions in alkaline solution but not in acidic solu β Coordination Compounds Chemistry Question
Question
Ammonia forms the complex [Cu(NH3)4]^2+ with copper ions in alkaline solution but not in acidic solution. The reason for this is :
Answer: D
π‘ Solution & Explanation
Step 1: Ammonia (NH3) is a Lewis base that coordinates to copper ions through the lone pair of electrons on its nitrogen atom. Step 2: In acidic solutions, the high concentration of protons (H^+) causes ammonia to undergo protonation to form the ammonium ion (NH4^+). Step 3: Because NH4^+ lacks a lone pair of electrons, it cannot coordinate to Cu^2+ ions. Therefore, ammonia coordinates with protons instead of forming the complex, which corresponds to option (d).
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