An ideal gas is expanded irreversibly from 5 L to 10 L against a constant external pressure of 1 bar β Thermodynamics and Thermochemistry Chemistry Question
Question
An ideal gas is expanded irreversibly from 5 L to 10 L against a constant external pressure of 1 bar. The value of heat involved (q) in this isenthalpic process is
Answer: B
π‘ Solution & Explanation
Isenthalpic process for ideal gas means Ξ H = 0, which implies Ξ T = 0 and Ξ U = 0. According to the First Law: Ξ U = q + w => 0 = q + w => q = -w. w = -P_ext * Ξ V = -1 bar * (10 - 5) L = -5 L-bar = -5 * 100 J = -500 J. Therefore, q = +500 J.
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