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💡 Solution & Explanation
3 6 B N H solution of hydrochloric acid ? Select ‘INCORRECT’ statement(s) about the above reaction: (A) No reaction (B) 3 3 6 B N H shows substitution reaction and forms 3 3 6 B N Cl (C) 3 3 6 B N H show addition reaction and produces 3 3 9 3 B N H Cl in which ‘Cl’-atoms are bonded to boron atoms. (D) 3 3 6 B N H shows addition reaction and produces 3 3 9 3 B N H Cl in which ‘Cl’-atoms are bonded to nitrogen atoms. AITS-OT-I (Paper-2)-PCM-JEE(Advanced)/22 Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942 website: www.fiitjee.com 16 Ans. A, B, D Sol. N B B N N B H H H H H H 3HCl N B B N N B H Cl H H H Cl H H Cl H H H Section – A (Maximum Marks: 12) This section contains TWO (02) paragraphs. Based on each paragraph, there are TWO (02) questions. Each question has FOUR options (A), (B), (C) and (D). ONLY ONE of these four options is the correct answer. Paragraph for Question Nos. 26 and 27 Consider the stereoisomer of iso-leucine labelled as below: NH2 OH O CH3 (P); NH2 OH O CH3 (Q); NH2 OH O CH3 (R); NH2 OH O CH3 (S) Consider the following data to answer the questions posted: (i) Set molar Gibb’s free energy of ‘P’, o 1 m G 0 kJ mol . (ii) The equilibrium constant eq K for epimerization of (P) has the value of 1.38 (at 374 K). (iii) Epimerization of (R) into (Q) follows first order kinetics with rate constant ‘k’ (at 374 K) = 5 1