What will be the colour of the solution when Mn(OH)2 is treated with concentrated HNO3 and sodium bi β Qualitative and Quantitative Analysis Chemistry Question
Question
What will be the colour of the solution when Mn(OH)2 is treated with concentrated HNO3 and sodium bismuthate (or red lead or lead dioxide)?
Answer: B
π‘ Solution & Explanation
Step 1: The brown ring test for nitrate ions results in the formation of a brown coordination complex. Step 2: The brown complex has the formula [Fe(H2O)5(NO)]2+. In this complex, nitric oxide transfers an electron to Fe2+ to become NO+, reducing the iron to a +1 oxidation state (Fe+). Step 3: Therefore, the oxidation state of Fe in the brown ring complex is +1, which corresponds to option (b).
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