Predict product(s) in the following reaction,<br>P + OH- Product(s) β p Block Elements Chemistry Question
Question
Predict product(s) in the following reaction,<br>P + OH- $\rightarrow$ Product(s)
Answer: A,C
π‘ Solution & Explanation
Step 1: Nitrogen trifluoride (NF3) lacks vacant d-orbitals on both nitrogen and fluorine atoms, preventing the coordinate attack of water (S_N2 pathway). Step 2: Under forcing conditions, if hydrolysis occurs, it is proposed to proceed via a unimolecular S_N1 pathway involving the slow dissociation of a fluoride ion. Step 3: Therefore, among the given halides, NF3 is the one that is considered to undergo hydrolysis via an S_N1 mechanism. Thus, the correct option is (b).
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