Study the following thermochemical data: S + -> ; δ H = -298.2 kJ; + 1/2 -> ; δ H = -98.2 kJ; + -> ; — Thermodynamics and Thermochemistry Chemistry Question
Question
Study the following thermochemical data: S + $O_2$ -> $SO_2$; δ H = -298.2 kJ; $SO_2$ + 1/2 $O_2$ -> $SO_3$; δ H = -98.2 kJ; $SO_3$ + $H_2O$ -> $H_2SO_4$; δ H = -130.2 kJ; $H_2$ + 1/2 $O_2$ -> $H_2O$; δ H = -287.3 kJ. The enthalpy of formation of $H_2SO_4$ at 298 K will be
Answer: D
💡 Solution & Explanation
We want the formation reaction of $H_2SO_4$: $H_2$(g) + S(s) + 2$O_2$(g) -> $H_2SO_4$(l). Adding the four given reactions together gives exactly this target equation. Thus, delta_f H° = -298.2 - 98.2 - 130.2 - 287.3 = -813.9 kJ/mol.
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