JEE Mains Chemistry Past PapershardMCQ SINGLE

Arrange the following Cobalt complexes in the order of increasing Crystal Field Stabilization EnergyJEE Mains Chemistry Past Papers Chemistry Question

Question

Arrange the following Cobalt complexes in the order of increasing Crystal Field Stabilization Energy (CFSE) value. Complexes : D 6 C 6 B 6 A 6 ] ) en ( Co [ and ] ) NH ( Co [, ] ) O H ( Co [, ] CoF [ Choose the correct option: fuEu dksckYV ladqyksa dks fØLVy {ks=k foikVu ÅtkZ (CFSE) ekuksa ds c<+rs Øe esa O;ofLFkr dhft,% ladqy : D 6 C 6 B 6 A 6 ] ) en ( Co [ ] ) NH ( Co [, ] ) O H ( Co [, ] CoF [ rFkk lgh fodYi pqfu,% (A) B < C < D < A (B) A < B < C < D (C) C < D < B < A (D) B < A < C < D

Answer: D

💡 Solution & Explanation

CFSE  strength of ligand en > NH3 > H2O > F– CFSE  oxidation number of central metal.  Order of CFSE   6 2 ] ) O H ( Co [ <   6 ] F Co [ <   6 3 ] ) NH ( Co [ <   6 ] ) en ( Co [

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