Atomic StructuremediumMCQ SINGLE

The wavelength of radiation emitted out in the transition to in ion isAtomic Structure Chemistry Question

Question

The wavelength of radiation emitted out in the transition $n=4$ to $n=1$ in $Li^{2+}$ ion is

Answer: B

💡 Solution & Explanation

By Rydberg formula, $\frac{1}{\lambda} = R Z^2 \left(\frac{1}{n_1^2} - \frac{1}{n_2^2}\right)$. For $Li^{2+}$, $Z=3$, so $\frac{1}{\lambda} = R (3)^2 \left(\frac{1}{1^2} - \frac{1}{4^2}\right) = 9R \left(1 - \frac{1}{16}\right) = 9R \left(\frac{15}{16}\right) = \frac{135 R}{16}$. Therefore, $\lambda = \frac{16}{135 R}$. Therefore, correct answer is B.

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