If 1% of a substance undergoing decomposition is consumed in 1 min, when the concentration is 0.02 M — Chemical Kinetics Chemistry Question
Question
If 1% of a substance undergoing decomposition is consumed in 1 min, when the concentration is 0.02 M and in 15 s, when the concentration is 0.04 M, the order of the reaction is
Answer: A
💡 Solution & Explanation
The time for a small fractional completion (like 1%) is proportional to the half-life. t_1% ∝ [A0]^(1-n). (1 min / 0.25 min) = (0.02 / 0.04)^(1-n) => 4 = (1/2)^(1-n) = 2^(n-1). Thus, n-1 = 2, giving n = 3. Therefore, correct answer is A.
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