SO3 gas is entering the environment at a constant rate of 6.93 × 10^-6 g/ l/day due to emission of p — Chemical Kinetics Chemistry Question
Question
SO3 gas is entering the environment at a constant rate of 6.93 × 10^-6 g/ l/day due to emission of polluting gases from thermal power plant at Kota, but at the same time it is decomposing and following first-order kinetics with half-life of 100 days. Based on these details, select the correct statement(s) from the following:
💡 Solution & Explanation
At steady state, Rate of formation = Rate of decomposition. 6.93 × 10^-6 g/L/day / 80 g/mol = K [SO3]. K = 0.693/100 day^-1. [SO3] = (6.93 × 10^-6 / 80) / (6.93 × 10^-3) = 1.25 × 10^-5 M. After 1000 days (10 half-lives), concentration reduces by 2^10 ≈ 1000, so 1.25 × 10^-8 M. Therefore, correct answer is A,D.