Chemical KineticshardCOMPREHENSIVE

The rate law will be if we simplify the rate law obtained in previous question assuming that the reaChemical Kinetics Chemistry Question

Question

The rate law will be if we simplify the rate law obtained in previous question assuming that the reactions (1) – (4) are much faster than reaction (5)

Answer: D

💡 Solution & Explanation

If reactions (1)-(4) are much faster than (5), then K4 >> K5[Cl2]. The denominator (K4 + K5[Cl2]) approximates to K4. Substituting this into the rate law from the previous question gives Rate = K5 K3 K1^1/2 [Cl2]^3/2 [CO] / (K4 K2^1/2). Therefore, correct answer is D.

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