Chemical KineticsmediumCOMPREHENSIVE

If rate constants for decomposition of N2O5, formation of NO2 and formation of O2 are K1, K2 and K3,Chemical Kinetics Chemistry Question

Question

If rate constants for decomposition of N2O5, formation of NO2 and formation of O2 are K1, K2 and K3, respectively, then

Answer: B

💡 Solution & Explanation

Rate of reaction = -1/2 d[N2O5]/dt = +1/4 d[NO2]/dt = +d[O2]/dt. Given the rate constants, this means 1/2 K1[N2O5] = 1/4 K2[N2O5] = K3[N2O5]. Thus, K1/2 = K2/4 = K3, which rearranges to 2K1 = K2 = 4K3. Therefore, correct answer is B.

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