Solutions and Colligative PropertiesmediumMCQ SINGLE

The elevation in boiling point, when 13.44 g of freshly prepared are added to one kg of water, is (SSolutions and Colligative Properties Chemistry Question

Question

The elevation in boiling point, when 13.44 g of freshly prepared $\text{CuCl}_2$ are added to one kg of water, is (Some useful data: $K_b \text{ of water} = 0.52 \text{ K - kg/mol}$; molecular weight of $\text{CuCl}_2 = 134.4$)

Answer: C

💡 Solution & Explanation

Moles of $\text{CuCl}_2 = 13.44 / 134.4 = 0.1 \text{ mol}$. Molality $m = 0.1 \text{ mol} / 1 \text{ kg} = 0.1 \text{ m}$. Assuming complete dissociation, $\text{CuCl}_2 \rightarrow \text{Cu}^{2+} + 2\text{Cl}^-$, giving $i=3$. $\Delta T_b = i \times K_b \times m = 3 \times 0.52 \times 0.1 = 0.156 \approx 0.16^\circ\text{C}$. Therefore, correct answer is C.

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