Solutions and Colligative PropertiesmediumMCQ SINGLE

The solution containing 4.0 g of PVC in 1 L of dioxane was found to have osmotic pressure of 0.006 aSolutions and Colligative Properties Chemistry Question

Question

The solution containing 4.0 g of PVC in 1 L of dioxane was found to have osmotic pressure of 0.006 atm at 300 K. The molecular mass of the polymer PVC is

Answer: A

💡 Solution & Explanation

$\pi = \frac{wRT}{MV} \implies M = \frac{wRT}{\pi V} = \frac{4.0 \times 0.0821 \times 300}{0.006 \times 1} = \frac{98.52}{0.006} = 16420$. Therefore, correct answer is A.

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