The density of solid argon is at . If the argon atoms are assumed to be spheres of radius , the appr — Solid State Chemistry Question
Question
The density of solid argon is $1.65 \text{ g/cm}^3$ at $-233^\circ\text{C}$. If the argon atoms are assumed to be spheres of radius $1.54 \times 10^{-8} \text{ cm}$, the approximate percentage of empty space in solid argon is (Ar = 40)
Answer: 0062
💡 Solution & Explanation
Volume of 1 mole of Ar = $40 / 1.65 = 24.24 \text{ cm}^3$. Volume occupied by the atoms = $N_A \times \frac{4}{3} \pi r^3 = 6.022 \times 10^{23} \times \frac{4}{3} \pi (1.54 \times 10^{-8})^3 \approx 9.21 \text{ cm}^3$. Packing fraction = $9.21 / 24.24 = 0.38$ (38%). Thus, the empty space is $100\% - 38\% = 62\%$. Therefore, correct answer is 0062.
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