ElectrochemistryhardMCQ SINGLE

Select the correct option if it is known that Ksp (AgCl) > Ksp (AgBr) > Ksp (AgI)Electrochemistry Chemistry Question

Question

Select the correct option if it is known that Ksp (AgCl) > Ksp (AgBr) > Ksp (AgI)

Answer: B

💡 Solution & Explanation

The standard potential of a metal-insoluble salt electrode is related to its solubility product by: E°_X-\|AgX\|Ag = E°_Ag+\|Ag + 0.0591 * log(Ksp). Since Ksp values follow the order AgCl > AgBr > AgI, their standard reduction potentials follow the exact same trend: E°_Cl-\|AgCl\|Ag > E°_Br-\|AgBr\|Ag > E°_I-\|AgI\|Ag. Therefore, correct answer is B.

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