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The current efficiency of an electrodeposition of copper metal in which 9.8 g of copper is depositedElectrochemistry Chemistry Question

Question

The current efficiency of an electrodeposition of copper metal in which 9.8 g of copper is deposited by a current of 3 A for 10000 s, from aqueous copper sulphate solution, is about

Answer: B

💡 Solution & Explanation

Theoretical mass = $ZIt = (E/96500) \times I \times t = (31.75 / 96500) \times 3 \times 10000 \approx 9.87$ g. Current efficiency = (Actual mass / Theoretical mass) $\times 100 = (9.8 / 9.87) \times 100 \approx 99.3\%$, which is closest to 99%. Therefore, correct answer is B.

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