Copper can be deposited from acidified copper sulphate and alkaline cuprous cyanide. If the same cur β Electrochemistry Chemistry Question
Question
Copper can be deposited from acidified copper sulphate and alkaline cuprous cyanide. If the same current is passed for a definite time
Answer: B
π‘ Solution & Explanation
According to Faraday's First Law, mass deposited is proportional to the equivalent weight. In copper sulphate, copper is $Cu^{2+}$ (eq. wt. = 63.5 / 2 = 31.75). In cuprous cyanide, copper is $Cu^+$ (eq. wt. = 63.5 / 1 = 63.5). Since the equivalent weight in cuprous cyanide is double, twice as much mass of copper will be deposited for the same electrical charge. Therefore, correct answer is B.
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