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Copper can be deposited from acidified copper sulphate and alkaline cuprous cyanide. If the same curElectrochemistry Chemistry Question

Question

Copper can be deposited from acidified copper sulphate and alkaline cuprous cyanide. If the same current is passed for a definite time

Answer: B

💡 Solution & Explanation

According to Faraday's First Law, mass deposited is proportional to the equivalent weight. In copper sulphate, copper is $Cu^{2+}$ (eq. wt. = 63.5 / 2 = 31.75). In cuprous cyanide, copper is $Cu^+$ (eq. wt. = 63.5 / 1 = 63.5). Since the equivalent weight in cuprous cyanide is double, twice as much mass of copper will be deposited for the same electrical charge. Therefore, correct answer is B.

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