ElectrochemistrymediumMCQ SINGLE

The standard reduction potentials in acidic conditions are 0.77 V and 0.53 V, respectively, for and Electrochemistry Chemistry Question

Question

The standard reduction potentials in acidic conditions are 0.77 V and 0.53 V, respectively, for $Fe^{3+} \| Fe^{2+}$ and $I_3^- \| I^-$ couples. The equilibrium constant for the reaction: $2Fe^{3+} + 3I^- \rightleftharpoons 2Fe^{2+} + I_3^-$, is ($2.303RT/F = 0.06$)

Answer: B

💡 Solution & Explanation

The standard cell potential $E^\circ_{cell} = E^\circ_{cathode} - E^\circ_{anode} = 0.77 - 0.53 = 0.24$ V. The number of electrons transferred is $n = 2$. Using the relation $\log K_c = \frac{nE^\circ}{0.06}$, we get $\log K_c = \frac{2 \times 0.24}{0.06} = 8$. Therefore, $K_c = 10^8$. Therefore, correct answer is B.

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