ElectrochemistrymediumMCQ SINGLE

For a reaction ; has been found to be . The EMF of the cell isElectrochemistry Chemistry Question

Question

For a reaction $A(s) + 2B^+ \rightarrow A^{2+} + B(s)$; $K_C$ has been found to be $10^{12}$. The EMF of the cell is

Answer: A

💡 Solution & Explanation

The relationship between standard EMF and equilibrium constant is $E^\circ = \frac{0.0591}{n} \log K_c$. Here, 2 electrons are transferred ($n=2$). $E^\circ = \frac{0.0591}{2} \log 10^{12} = 0.02955 \times 12 = 0.3546$ V, which approximates to 0.354 V. Therefore, correct answer is A.

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