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The solution of CuSO4, in which copper rod is immersed, is diluted to 10 times. The reduction electrElectrochemistry Chemistry Question

Question

The solution of CuSO4, in which copper rod is immersed, is diluted to 10 times. The reduction electrode potential

Answer: B

💡 Solution & Explanation

The reduction reaction is $Cu^{2+} + 2e^- \rightarrow Cu$. $E = E^\circ - (0.0591/2) \log(1/[Cu^{2+}])$. Diluting 10 times makes the new concentration $[Cu^{2+}]/10$. The change in the log term is $\log(10) = 1$. The change in potential is $-(0.0591/2) \times 1 = -0.02955$ V. It decreases by approximately 0.0295 V.

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