If a current of 1.0 A is drawn from the Daniel cell for 96.5 min, the cathode will gain in weight by — Electrochemistry Chemistry Question
Question
If a current of 1.0 A is drawn from the Daniel cell for 96.5 min, the cathode will gain in weight by (Cu = 63.5, Zn = 65.4)
Answer: A
💡 Solution & Explanation
Charge $Q = I \times t = 1.0 \times (96.5 \times 60) = 5790$ C. Number of Faradays = $5790 / 96500 = 0.06$ F. In a Daniel cell, Cu is deposited at the cathode: $Cu^{2+} + 2e^- \rightarrow Cu$. Moles of Cu deposited = $0.06 / 2 = 0.03$ mol. Weight gained = $0.03 \times 63.5 = 1.905$ g. Therefore, correct answer is A.
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